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Literature summary extracted from

  • Pasta, P.; Carrea, G.; Holland, H.L.; Dallavalle, S.
    Synthesis of chiral benzyl alkyl sulfoxides by cyclohexanone monooxygenase from Acinetobacter NCIB 9871 (1995), Tetrahedron, 6, 933-936.
No PubMed abstract available

Organism

EC Number Organism UniProt Comment Textmining
1.14.13.22 Acinetobacter sp.
-
 NCIB 9871
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Reaction

EC Number Reaction Comment Organism Reaction ID
1.14.13.22 cyclohexanone + NADPH + H+ + O2 = hexano-6-lactone + NADP+ + H2O stereochemistry and enantioselectivity of the oxidation reaction depends strongly on the structure and stereochemistry of the substrates Acinetobacter sp.
a

Substrates and Products (Substrate)

EC Number Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
1.14.13.22 2-phenylethyl methyl sulfide + NADPH + O2
-
 Acinetobacter sp. 2-phenylethyl methyl sulfoxide
-
 ?
1.14.13.22 2-phenylpropyl methyl sulfide + NADPH + O2
-
 Acinetobacter sp. 2-phenylpropyl methyl sulfoxide
-
 ?
1.14.13.22 cyclohexanone + NADPH + O2
-
 Acinetobacter sp. 6-hexanolide + NADP+ + H2O
-
 ?
1.14.13.22 additional information high enantioselectivity in oxidation of sulfides Acinetobacter sp. ?
-
 ?
1.14.13.22 additional information active with benzyl alkyl sulfides with alkyl groups from methyl to hexyl and para-alkylbenzyl groups from methyl to butyl Acinetobacter sp. ?
-
 ?