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Literature summary extracted from
- Functional group diversity in enzymatic oxygenation reactions catalyzed by bacterial flavin-containing cyclohexanone oxygenase (1985), J. Am. Chem. Soc., 107, 2153-2161.
No PubMed abstract available
KM Value [mM]
| EC Number | KM Value [mM] | KM Value Maximum [mM] | Substrate | Comment | Organism | Structure |
|---|---|---|---|---|---|---|
| 1.14.13.22 | 0.0025 | - |
n-Octylboronic acid | - |
Acinetobacter sp. |  |
| 1.14.13.22 | 0.006 | - |
cyclohexanone | - |
Acinetobacter sp. | |
| 1.14.13.22 | 0.009 | - |
n-Butylboronic acid | - |
Acinetobacter sp. | |
| 1.14.13.22 | 0.024 | - |
Thiane | - |
Acinetobacter sp. | |
| 1.14.13.22 | 0.025 | - |
Butanal | - |
Acinetobacter sp. | |
| 1.14.13.22 | 0.03 | - |
Phenyl allyl selenide | - |
Acinetobacter sp. | |
| 1.14.13.22 | 0.043 | - |
phenylboronic acid | - |
Acinetobacter sp. | |
| 1.14.13.22 | 0.044 | - |
Phenyl methyl selenide | - |
Acinetobacter sp. | |
| 1.14.13.22 | 0.11 | - |
Phenyl allyl sulfide | - |
Acinetobacter sp. | |
| 1.14.13.22 | 0.178 | - |
Thiane sulfoxide | - |
Acinetobacter sp. | |
| 1.14.13.22 | 0.22 | - |
ethyl p-tolyl sulfide | - |
Acinetobacter sp. | |
| 1.14.13.22 | 0.33 | - |
1-Phenyl-2-propanone | - |
Acinetobacter sp. | |
| 1.14.13.22 | 0.35 | - |
2-Phenyl-1-ethanal | - |
Acinetobacter sp. | |
| 1.14.13.22 | 0.36 | - |
triethyl phosphite | - |
Acinetobacter sp. | |
| 1.14.13.22 | 2.5 | - |
Iodide | - |
Acinetobacter sp. | |
Organism
| EC Number | Organism | UniProt | Comment | Textmining |
|---|---|---|---|---|
| 1.14.13.22 | Acinetobacter sp. | - |
NCIB 9871 | - |
Reaction
| EC Number | Reaction | Comment | Organism | Reaction ID |
|---|---|---|---|---|
| 1.14.13.22 | cyclohexanone + NADPH + H+ + O2 = hexano-6-lactone + NADP+ + H2O | general mechanistic scheme | Acinetobacter sp. |
Substrates and Products (Substrate)
| EC Number | Substrates | Comment Substrates | Organism | Products | Comment (Products) | Rev. | Reac. |
|---|---|---|---|---|---|---|---|
| 1.14.13.22 | 1-phenyl-2-propanone + NADPH + O2 | - |
Acinetobacter sp. | ? | - |
? | |
| 1.14.13.22 | 2-phenyl-1-ethanal + NADPH + O2 | - |
Acinetobacter sp. | ? | - |
? | |
| 1.14.13.22 | butanal + NADPH + O2 | - |
Acinetobacter sp. | ? | - |
? | |
| 1.14.13.22 | cyclohexanone + NADPH + O2 | - |
Acinetobacter sp. | 6-hexanolide + NADP+ + H2O | - |
? | |
| 1.14.13.22 | ethyl p-tolyl sulfide + NADPH + O2 | - |
Acinetobacter sp. | (S)-ethyl p-tolyl sulfoxide + NADP+ + H2O | - |
? | |
| 1.14.13.22 | iodide + NADPH + O2 | - |
Acinetobacter sp. | ? | - |
? | |
| 1.14.13.22 | n-butylboronic acid + NADPH + O2 | - |
Acinetobacter sp. | n-butanol + BO3- + NADP+ + H2O | - |
? | |
| 1.14.13.22 | n-octylboronic acid + NADPH + O2 | - |
Acinetobacter sp. | n-octanol + BO3- + NADP+ + H2O | - |
? | |
| 1.14.13.22 | phenyl allyl selenide + NADPH + O2 | - |
Acinetobacter sp. | ? | - |
? | |
| 1.14.13.22 | phenyl allyl sulfide + NADPH + O2 | - |
Acinetobacter sp. | ? | - |
? | |
| 1.14.13.22 | phenyl methyl selenide + NADPH + O2 | - |
Acinetobacter sp. | ? | - |
? | |
| 1.14.13.22 | phenylboronic acid + NADPH + O2 | - |
Acinetobacter sp. | phenol + BO3- + NADP+ + H2O | - |
? | |
| 1.14.13.22 | thiane + NADPH + O2 | - |
Acinetobacter sp. | ? | - |
? | |
| 1.14.13.22 | thiane sulfoxide + NADPH + O2 | - |
Acinetobacter sp. | ? | - |
? | |
| 1.14.13.22 | triethylphosphite + NADPH + O2 | - |
Acinetobacter sp. | ? | - |
? | |
Cofactor
| EC Number | Cofactor | Comment | Organism | Structure |
|---|---|---|---|---|
| 1.14.13.22 | FAD | - |
Acinetobacter sp. | |
| 1.14.13.22 | NADPH | - |
Acinetobacter sp. | |
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