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Literature summary extracted from
- Metabolism of aromatic compounds by fungi. Kinetic properties and mechanism of 3-carboxy-cis,cis-muconate cyclase from Aspergillus niger (1975), Eur. J. Biochem., 56, 193-204.
General Stability
| EC Number | General Stability | Organism |
|---|---|---|
| 5.5.1.5 | rose-bengal-sensitized photooxidation | Aspergillus niger |
Inhibitors
| EC Number | Inhibitors | Comment | Organism | Structure |
|---|---|---|---|---|
| 5.5.1.5 | 2-Chloro-4-methylmuconolactone | non-competitive | Aspergillus niger |  |
| 5.5.1.5 | 3-chloromuconate | competitive | Aspergillus niger | |
| 5.5.1.5 | 3-Chloromuconolactone | non-competitive | Aspergillus niger | |
| 5.5.1.5 | 3-methylmuconate | competitive | Aspergillus niger | |
| 5.5.1.5 | adipate | - |
Aspergillus niger | |
| 5.5.1.5 | AsO2- | - |
Aspergillus niger | |
| 5.5.1.5 | AsO43- | - |
Aspergillus niger | |
| 5.5.1.5 | BO33- | negligible effect near the pH optimum but inhibits to a greater extent on the acid side of the optimum | Aspergillus niger | |
| 5.5.1.5 | Br- | - |
Aspergillus niger | |
| 5.5.1.5 | cis-aconitate | - |
Aspergillus niger | |
| 5.5.1.5 | citraconate | - |
Aspergillus niger | |
| 5.5.1.5 | citrate | - |
Aspergillus niger | |
| 5.5.1.5 | ethoxyformic anhydride | irreversible, presence of the competitive inhibitors cis-aconitate, trans-aconitate and cis,cis-muconate conferrs some protection | Aspergillus niger | |
| 5.5.1.5 | F- | - |
Aspergillus niger | |
| 5.5.1.5 | fumarate | - |
Aspergillus niger | |
| 5.5.1.5 | glutaconate | - |
Aspergillus niger | |
| 5.5.1.5 | Glutarate | - |
Aspergillus niger | |
| 5.5.1.5 | H2PO2- | negligible effect near the pH optimum but inhibits to a greater extent on the acid side of the optimum | Aspergillus niger | |
| 5.5.1.5 | I- | - |
Aspergillus niger | |
| 5.5.1.5 | Itaconate | - |
Aspergillus niger | |
| 5.5.1.5 | malate | - |
Aspergillus niger | |
| 5.5.1.5 | Maleate | - |
Aspergillus niger | |
| 5.5.1.5 | malonate | - |
Aspergillus niger | |
| 5.5.1.5 | mesaconate | - |
Aspergillus niger | |
| 5.5.1.5 | NO2- | - |
Aspergillus niger | |
| 5.5.1.5 | NO3- | - |
Aspergillus niger | |
| 5.5.1.5 | oxalate | - |
Aspergillus niger | |
| 5.5.1.5 | phosphate | negligible effect near the pH optimum but inhibits to a greater extent on the acid side of the optimum | Aspergillus niger | |
| 5.5.1.5 | pimelate | - |
Aspergillus niger | |
| 5.5.1.5 | S2O32- | negligible effect near the pH optimum but inhibits to a greater extent on the acid side of the optimum | Aspergillus niger | |
| 5.5.1.5 | SO42- | - |
Aspergillus niger | |
| 5.5.1.5 | succinate | - |
Aspergillus niger | |
| 5.5.1.5 | Tartrate | - |
Aspergillus niger | |
| 5.5.1.5 | trans,trans-muconate | - |
Aspergillus niger | |
| 5.5.1.5 | trans-aconitate | - |
Aspergillus niger | |
KM Value [mM]
| EC Number | KM Value [mM] | KM Value Maximum [mM] | Substrate | Comment | Organism | Structure |
|---|---|---|---|---|---|---|
| 5.5.1.5 | 0.057 | - |
3-carboxy-cis,cis-muconate | - |
Aspergillus niger | |
Organism
| EC Number | Organism | UniProt | Comment | Textmining |
|---|---|---|---|---|
| 5.5.1.5 | Aspergillus niger | - |
- |
- |
Substrates and Products (Substrate)
| EC Number | Substrates | Comment Substrates | Organism | Products | Comment (Products) | Rev. | Reac. |
|---|---|---|---|---|---|---|---|
| 5.5.1.5 | 3-Carboxy-cis,cis-muconate | - |
Aspergillus niger | 3-Carboxy-5-oxo-2,5-dihydrofuran-2-acetate | - |
? | |
pH Optimum
| EC Number | pH Optimum Minimum | pH Optimum Maximum | Comment | Organism |
|---|---|---|---|---|
| 5.5.1.5 | 5.5 | 6 | - |
Aspergillus niger |
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Release 2023.1 (January 2023)
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