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Literature summary for 5.5.1.2 extracted from

  • Chari, R.V.J.; Whitman, C.P.; Kozarich, J.W.; Ngai, K.L.; Ornston, L.N.
    Absolute stereochemical course of the 3-carboxymuconate cycloisomerase from Pseudomonas putida and Acinetobacter calcoaceticus: analysis and implications (1987), J. Am. Chem. Soc., 109, 5514-5519.
No PubMed abstract available
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Organism

Organism UniProt Comment Textmining
Acinetobacter calcoaceticus
-
-
-
Pseudomonas putida
-
-
-

Reaction

Reaction Comment Organism Reaction ID
cis,cis-butadiene-1,2,4-tricarboxylate = 2-carboxy-2,5-dihydro-5-oxofuran-2-acetate lactonization proceeds by an anti-addition Pseudomonas putida
a
cis,cis-butadiene-1,2,4-tricarboxylate = 2-carboxy-2,5-dihydro-5-oxofuran-2-acetate lactonization proceeds by an anti-addition Acinetobacter calcoaceticus
a

Substrates and Products (Substrate)

Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
2-Carboxy-2,5-dihydro-5-oxofuran-2-acetate i.e. beta-carboxy-cis,cis-muconate Pseudomonas putida cis-Butadiene-1,2,4-tricarboxylate (4R,5R)-4-carboxymuconate ?
2-Carboxy-2,5-dihydro-5-oxofuran-2-acetate i.e. beta-carboxy-cis,cis-muconate Acinetobacter calcoaceticus cis-Butadiene-1,2,4-tricarboxylate (4R,5R)-4-carboxymuconate ?
2-Carboxy-2,5-dihydro-5-oxofuran-2-acetate i.e. beta-carboxy-cis,cis-muconate Pseudomonas putida cis-Butadiene-1,2,4-tricarboxylate i.e. gamma-carboxymuconolactone ?
2-Carboxy-2,5-dihydro-5-oxofuran-2-acetate i.e. beta-carboxy-cis,cis-muconate Acinetobacter calcoaceticus cis-Butadiene-1,2,4-tricarboxylate i.e. gamma-carboxymuconolactone ?