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Literature summary for 5.4.99.17 extracted from

  • Hammer, S.; Dominicus, J.; Syrén, P.; Nestl, B.; Hauer, B.
    Stereoselective Friedel-Crafts alkylation catalyzed by squalene hopene cyclases (2012), Tetrahedron, 68, 7624-7629.
No PubMed abstract available
Search for more literature for 5.4.99.17

Natural Substrates/ Products (Substrates)

Natural Substrates Organism Comment (Nat. Sub.) Natural Products Comment (Nat. Pro.) Rev. Reac.
squalene Zymomonas mobilis
-
 hop-22(29)-ene + hopanol
-
 ?
squalene Zymomonas mobilis CP4
-
 hop-22(29)-ene + hopanol
-
 ?

Organism

Organism UniProt Comment Textmining
Zymomonas mobilis Q5NM88 gene ZMO1548
-
Zymomonas mobilis CP4 Q5NM88 gene ZMO1548
-

Reaction

Reaction Comment Organism Reaction ID
squalene = hop-22(29)-ene catalytic mechanism via Friedel-Crafts alkylation and substrate specificity, overview Zymomonas mobilis
a

Substrates and Products (Substrate)

Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
citronellal
-
 Zymomonas mobilis isopulegol i.e. 2-isopropenyl-5-methyl-cyclohexanol ?
citronellal
-
 Zymomonas mobilis CP4 isopulegol i.e. 2-isopropenyl-5-methyl-cyclohexanol ?
farnesyl phenyl ether
-
 Zymomonas mobilis (4aS,5S,8aS)-1,1,4a,6-tetramethyl-5-(phenoxymethyl)-1,2,3,4,4a,5,8,8a-octahydronaphthalene + (4aS,4bR,10bR,12aS)-1,1,4a,10b-tetramethyl-2,3,4,4a,4b,5,10b,11,12,12a-decahydro-1H-naphtho[1,2-c]chromene
-
 ?
farnesyl phenyl ether
-
 Zymomonas mobilis CP4 (4aS,5S,8aS)-1,1,4a,6-tetramethyl-5-(phenoxymethyl)-1,2,3,4,4a,5,8,8a-octahydronaphthalene + (4aS,4bR,10bR,12aS)-1,1,4a,10b-tetramethyl-2,3,4,4a,4b,5,10b,11,12,12a-decahydro-1H-naphtho[1,2-c]chromene
-
 ?
geranyl phenyl ether
-
 Zymomonas mobilis (6aS,10aS)-7,7,10a-trimethyl-6a,7,8,9,10,10a-hexahydro-6H-benzo[c]chromene
-
 ?
geranyl phenyl ether
-
 Zymomonas mobilis CP4 (6aS,10aS)-7,7,10a-trimethyl-6a,7,8,9,10,10a-hexahydro-6H-benzo[c]chromene
-
 ?
geranylgeranyl phenyl ether
-
 Zymomonas mobilis (14b)-8,13-dimethyl-14-(phenoxymethyl)podocarp-12-ene + (14b)-8-methyl-13-methylidene-14-(phenoxymethyl)podocarpane
-
 ?
homofarnesol
-
 Zymomonas mobilis ambroxan
-
 ?
additional information substrate specificity, overview. No activity with prenyl phenyl ether Zymomonas mobilis ?
-
 ?
additional information substrate specificity, overview. No activity with prenyl phenyl ether Zymomonas mobilis CP4 ?
-
 ?
squalene
-
 Zymomonas mobilis hop-22(29)-ene + hopanol
-
 ?
squalene
-
 Zymomonas mobilis CP4 hop-22(29)-ene + hopanol
-
 ?

Synonyms

Synonyms Comment Organism
SHC
-
 Zymomonas mobilis
squalene hopene cyclase
-
 Zymomonas mobilis
ZmSHC1
-
 Zymomonas mobilis