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Literature summary for 5.3.2.6 extracted from

  • Radivojevic, J.; Minovska, G.; Senerovic, L.; OConnor, K.; Jovanovic, P.; Savic, V.; Tokic-Vujosevic, Z.; Nikodinovic-Runic, J.; Maslak, V.
    Synthesis of gamma-nitroaldehydes containing quaternary carbon in the alpha-position using a 4-oxalocrotonate tautomerase whole-cell biocatalyst (2014), RSC Adv., 4, 60502-60510 .
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Cloned(Commentary)

Cloned (Comment) Organism
expressed in Escherichia coli BL21(DE3) cells Pseudomonas putida

Natural Substrates/ Products (Substrates)

Natural Substrates Organism Comment (Nat. Sub.) Natural Products Comment (Nat. Pro.) Rev. Reac.
(2Z,4E)-2-hydroxyhexa-2,4-dienedioate Pseudomonas putida
-
 (3E)-2-oxohex-3-enedioate
-
 r

Organism

Organism UniProt Comment Textmining
Pseudomonas putida
-
-
-

Substrates and Products (Substrate)

Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
(2Z,4E)-2-hydroxyhexa-2,4-dienedioate
-
 Pseudomonas putida (3E)-2-oxohex-3-enedioate
-
 r
(E)-2-(furan-2-yl)nitroethene + isobutanal
-
 Pseudomonas putida 3-(furan-2-yl)-2,2-dimethyl-4-nitrobutanal
-
 ?
(E)-2-(thiophen-2-yl)nitroethene + isobutanal
-
 Pseudomonas putida 2,2-dimethyl-4-nitro-3-(thiophen-2-yl)butanal
-
 ?
3,4-(methylenedioxy)-beta-nitrostyrene + isobutanal
-
 Pseudomonas putida (3E)-3-(2H-1,3-benzodioxol-5-yl)-2,2-dimethyl-4-nitrobut-3-enal
-
 ?
isobutanal + beta-nitrostyrene
-
 Pseudomonas putida 2,2-dimethyl-4-nitro-3-phenylbutanal + 4-nitro-3-phenylbutanal
-
 ?
additional information no activity with (E)-2-cyclohexyl-1-nitroethene Pseudomonas putida ?
-
 ?
trans-p-chloro-beta-nitrostyrene + isobutanal
-
 Pseudomonas putida 3-(4-chlorophenyl)-2,2-dimethyl-4-nitrobutanal
-
 ?

Synonyms

Synonyms Comment Organism
4-OT
-
 Pseudomonas putida
4-oxalocrotonate tautomerase
-
 Pseudomonas putida