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Literature summary for 4.2.3.119 extracted from

  • Bohlmann, J.; Phillips, M.; Ramachandiran, V.; Katoh, S.; Croteau, R.
    cDNA cloning, characterization, and functional expression of four new monoterpene synthase members of the Tpsd gene family from grand fir (Abies grandis) (1999), Arch. Biochem. Biophys., 368, 232-243.
    View publication on PubMed

Cloned(Commentary)

Cloned (Comment) Organism
expression in Escherichia coli Abies grandis

Molecular Weight [Da]

Molecular Weight [Da] Molecular Weight Maximum [Da] Comment Organism
70750
-
x * 70750, calculated Abies grandis

Organism

Organism UniProt Comment Textmining
Abies grandis Q948Z0
-
-
Abies grandis Q9M7D0
-
-

Posttranslational Modification

Posttranslational Modification Comment Organism
proteolytic modification sequence contains a putative N-terminal targeting peptide Abies grandis
proteolytic modification sequence contains a putative plastid targeting signal Abies grandis

Substrates and Products (Substrate)

Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
geranyl diphosphate
-
Abies grandis (-)-alpha-pinene + diphosphate 42% terpinolene, 18% (-)-alpha-pinene, 11% (-)-limonene, 10% (-)-beta-pinene plus several minor products ?
geranyl diphosphate
-
Abies grandis (-)-alpha-pinene + diphosphate products are 54% (-)-(1S,4R)-camphene, followed by 32% (-)-(1S,5S)-alpha-pinene and 7% (-)-(4S)-limonene. (+)-alpha-pinene is produced to about 5% of (-)-alpha-pinene ?
additional information entire product set is derived in stereochemically consistent fashion via (-)-3S-linalyl diphosphate as intermediate Abies grandis ?
-
?

Subunits

Subunits Comment Organism
? x * 70750, calculated Abies grandis

Synonyms

Synonyms Comment Organism
ag6
-
Abies grandis
ag9
-
Abies grandis
camphene synthase
-
Abies grandis