Literature summary for 4.2.3.119 extracted from

Croteau, R.; Wheeler, C.J.
Isotopically sensitive branching in the formation of cyclic monoterpenes: Proof that (-)-alpha-pinene and (-)-beta-pinene are synthesized by the same monoterpene cyclase via deprotonation of a common intermediate (1987), Biochemistry, 26, 5383-5389.

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Organism

Organism	UniProt	Comment	Textmining
Salvia officinalis	-	-	-

Substrates and Products (Substrate)

Substrates	Comment Substrates	Organism	Products	Comment (Products)	Rev.	Reac.
geranyl diphosphate	-	Salvia officinalis	(-)-alpha-pinene + diphosphate	main products are (-)-alpha-pinene, (-)-beta-pinene and camphene. Primary deuterium isotope effects suggest that (-)-alpha-pinene and (-)-beta-pinene derive from alternative deprotonation of a common enzymatic intermediate	?

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Release 2023.1 (January 2023)