Natural Substrates | Organism | Comment (Nat. Sub.) | Natural Products | Comment (Nat. Pro.) | Rev. | Reac. |
---|---|---|---|---|---|---|
CDP-glucose | Yersinia pseudotuberculosis | biosynthetic pathway of 3,6-dideoxysugars | ? | - |
? |
Organism | UniProt | Comment | Textmining |
---|---|---|---|
Yersinia pseudotuberculosis | - |
Pasteurella pseudotuberculosis | - |
Reaction | Comment | Organism | Reaction ID |
---|---|---|---|
CDP-glucose = CDP-4-dehydro-6-deoxy-D-glucose + H2O | stereochemistry, intramolecular oxidation-reduction that involves an internal hydrogen transfer from C-4 of the substrate to C-6 of the resulting product | Yersinia pseudotuberculosis |
Substrates | Comment Substrates | Organism | Products | Comment (Products) | Rev. | Reac. |
---|---|---|---|---|---|---|
CDP-D-glucose | - |
Yersinia pseudotuberculosis | CDP-4-dehydro-6-deoxy-D-glucose + H2O | CDP-6-deoxy-D-glycero-L-threo-4-hexulose | ? | |
CDP-glucose | biosynthetic pathway of 3,6-dideoxysugars | Yersinia pseudotuberculosis | ? | - |
? |
Cofactor | Comment | Organism | Structure |
---|---|---|---|
NAD+ | catalytic prosthetic group, NAD+ serves as a hydride carrier receiving the 4H of the substrate in the oxidative half-reaction and passing the reducing equivalents to C-6 in the reductive half-reaction, the substrate is bound to the si-face of the nicotinamide ring | Yersinia pseudotuberculosis |