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Literature summary for 4.1.99.19 extracted from

  • Kriek, M.; Martins, F.; Challand, M.R.; Croft, A.; Roach, P.L.
    Thiamine biosynthesis in Escherichia coli: identification of the intermediate and by-product derived from tyrosine (2007), Angew. Chem. Int. Ed. Engl., 46, 9223-9226.
    View publication on PubMed

Metals/Ions

Metals/Ions Comment Organism Structure
4Fe-4S cluster
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Escherichia coli

Organism

Organism UniProt Comment Textmining
Escherichia coli P30140
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-

Substrates and Products (Substrate)

Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
L-tyrosine + S-adenosyl-L-methionine + reduced acceptor the reductive cleavage of S-adenosyl-L-methionine yields the highly reactive 5'-deoxyadenosyl radical, which can abstract the phenolic hydrogen atom from tyrosine Escherichia coli 2-iminoacetate + 4-methylphenol + 5'-deoxyadenosine + L-methionine + acceptor + 2 H+
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Synonyms

Synonyms Comment Organism
thiH
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Escherichia coli