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Literature summary for 4.1.2.19 extracted from

  • Garrabou, X.; Calveras, J.; Joglar, J.; Parella, T.; Bujons, J.; Clapes, P.
    Highly efficient aldol additions of DHA and DHAP to N-Cbz-amino aldehydes catalyzed by L-rhamnulose-1-phosphate and L-fuculose-1-phosphate aldolases in aqueous borate buffer (2011), Org. Biomol. Chem., 9, 8430-8436.
    View publication on PubMed
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Organism

Organism UniProt Comment Textmining
Escherichia coli
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Substrates and Products (Substrate)

Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
dihydroxyacetone phosphate + N-Cbz-(2R)-2-amino-3-methylbutanal
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 Escherichia coli N-Cbz-5-amino-1,3,4-trihydroxyoctan-2-one yield 93%, ratio of (3R,4S) to (3S,4R) product is 2:98 ?
dihydroxyacetone phosphate + N-Cbz-(2S)-2-amino-3-methylbutanal
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 Escherichia coli N-Cbz-5-amino-1,3,4-trihydroxyoctan-2-one yield 93%, ratio of (3R,4S) to (3S,4R) product is 98:2 ?
dihydroxyacetone phosphate + N-Cbz-(2S)-2-aminobutanal
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 Escherichia coli N-Cbz-5-amino-1,3,4-trihydroxyheptan-2-one yield 94%, ratio of (3R,4S) to (3S,4R) product is 98:2 ?
dihydroxyacetone phosphate + N-Cbz-(2S)-2-aminopropanal
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 Escherichia coli N-Cbz-5-amino-1,3,4-trihydroxyhexan-2-one yield 99%, ratio of (3R,4S) to (3S,4R) product is 98:2 ?
dihydroxyacetone phosphate + N-Cbz-aminoacetaldehyde yield 91%, ratio of (3R,4S) to (3S,4R) product is 94:6 Escherichia coli N-Cbz-5-amino-1,3,4-trihydroxypentan-2-one yield 91%, ratio of (3R,4S) to (3S,4R) product is 94:6 ?