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Literature summary for 4.1.2.10 extracted from

  • Gaisberger, R.P.; Fechter, M.H.; Griengl, H.
    The first hydroxynitrile lyase catalysed cyanohydrin formation in ionic liquids (2004), Tetrahedron, 15, 2959-2963.
No PubMed abstract available

Activating Compound

Activating Compound Comment Organism Structure
additional information reaction in a two phase solvent system aqueous buffer and ionic liquid. When compared to the use of organic solvents as the nonaqueous phase, the reaction rate is significantly increased whereas the enantioselectivity remained good Prunus dulcis

Organism

Organism UniProt Comment Textmining
Prunus dulcis
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Substrates and Products (Substrate)

Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
HCN + benzaldehyde reaction in a two phase solvent system aqueous buffer and ionic liquid. When compared to the use of organic solvents as the nonaqueous phase, the reaction rate is significantly increased whereas the enantioselectivity remains good Prunus dulcis (R)-mandelonitrile
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?
HCN + decanal reaction in a two phase solvent system aqueous buffer and ionic liquid. When compared to the use of organic solvents as the nonaqueous phase, the reaction rate is significantly increased whereas the enantioselectivity remains good Prunus dulcis (R)-2-hydroxyundecanenitrile
-
?
HCN + dodecanal reaction in a two phase solvent system aqueous buffer and ionic liquid. When compared to the use of organic solvents as the nonaqueous phase, the reaction rate is significantly increased whereas the enantioselectivity remains good Prunus dulcis (R)-2-hydroxytridecanenitrile
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?
HCN + undecanal reaction in a two phase solvent system aqueous buffer and ionic liquid. When compared to the use of organic solvents as the nonaqueous phase, the reaction rate is significantly increased whereas the enantioselectivity remains good Prunus dulcis (R)-2-hydroxydodecanenitrile
-
?