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Literature summary for 4.1.1.77 extracted from

  • Stanley, T.M.; Johnson, W.H., Jr.; Burks, E.A.; Whitman, C.P.; Hwang, C.C.; Cook, P.F.
    Expression and stereochemical and isotope effect studies of active 4-oxalocrotonate decarboxylase (2000), Biochemistry, 39, 718-726.
    View publication on PubMed
Search for more literature for 4.1.1.77

Cloned(Commentary)

Cloned (Comment) Organism
-
 Pseudomonas putida

KM Value [mM]

KM Value [mM] KM Value Maximum [mM] Substrate Comment Organism Structure
68
-
 2-oxo-3-hexenedioate pH 7.3 Pseudomonas putida

Organism

Organism UniProt Comment Textmining
Pseudomonas putida
-
 mt-2
-
Pseudomonas putida mt-2 / ATCC 33015 / DSM 3931 / NCIB 12182 / NCIMB 12182
-
 mt-2
-

Purification (Commentary)

Purification (Comment) Organism
complex with vinylpyruvate hydratase, homogenetiy Pseudomonas putida

Reaction

Reaction Comment Organism Reaction ID
(3E)-2-oxohex-3-enedioate = 2-oxopent-4-enoate + CO2 mechanism Pseudomonas putida
a

Substrates and Products (Substrate)

Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
2-oxo-3-hexenedioate 4-OD and vinylpyruvate hydratase form a complex, 2-hydroxy-2,4-pentadienoate is the product of 4-OD and 2-oxo-4-pentenoate results from a vinylpyruvate hydratase-catalyzed process Pseudomonas putida 2-oxopent-4-enoate + CO2
-
 ?
2-oxo-3-hexenedioate 4-OD and vinylpyruvate hydratase form a complex, 2-hydroxy-2,4-pentadienoate is the product of 4-OD and 2-oxo-4-pentenoate results from a vinylpyruvate hydratase-catalyzed process Pseudomonas putida mt-2 / ATCC 33015 / DSM 3931 / NCIB 12182 / NCIMB 12182 2-oxopent-4-enoate + CO2
-
 ?

Synonyms

Synonyms Comment Organism
4-OD
-
 Pseudomonas putida

Turnover Number [1/s]

Turnover Number Minimum [1/s] Turnover Number Maximum [1/s] Substrate Comment Organism Structure
68
-
 2-oxo-3-hexenedioate
-
 Pseudomonas putida