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Literature summary for 4.1.1.7 extracted from

  • Dominguez de Maria, P.; Pohl, M.; Gocke, D.; Groeger, H.; Trauthwein, H.; Stillger, T.; Walter, L.; Mueller, M.
    Asymmetric synthesis of aliphatic 2-hydroxy ketones by enzymatic carboligation of aldehydes (2007), Eur. J. Org. Chem., 2007, 2940-2944.
No PubMed abstract available

Metals/Ions

Metals/Ions Comment Organism Structure
Mg2+ dependent Pseudomonas putida

Organism

Organism UniProt Comment Textmining
Pseudomonas putida
-
-
-

Substrates and Products (Substrate)

Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
acetaldehyde
-
Pseudomonas putida (R)-acetoin
-
?
benzoylformate
-
Pseudomonas putida benzaldehyde + CO2
-
?
isovaleraldehyde
-
Pseudomonas putida (R)-5-hydroxy-2,7-dimethyloctan-4-one
-
?
additional information isobutyraldehyde, pivalaldehyde, and tert-butylacetaldehyde are no substrates Pseudomonas putida ?
-
?
n-butanal
-
Pseudomonas putida (R)-5-hydroxyoctan-4-one
-
?
n-pentanal
-
Pseudomonas putida (R)-6-hydroxydecan-5-one
-
?
propanal
-
Pseudomonas putida 4-hydroxyhexan-3-one
-
?

Synonyms

Synonyms Comment Organism
BFD catalyzes the asymmetric ligation of aliphatic aldehydes to afford enantiomerically enriched 2-hydroxy ketones Pseudomonas putida

Cofactor

Cofactor Comment Organism Structure
thiamine diphosphate dependent Pseudomonas putida