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Literature summary for 4.1.1.7 extracted from

  • Demir, A.S.; Dünnwald, T.; Iding, H.; Pohl, M.; Müller, M.
    Asymmetric benzoin reaction catalyzed by benzoylformate decarboxylase (1999), Tetrahedron, 10, 4769-4774.
No PubMed abstract available
Search for more literature for 4.1.1.7

Application

Application Comment Organism
synthesis enzyme-catalyzed synthesis of enantiomerically pure (R)-benzoin derivatives in good yield Pseudomonas putida

Organism

Organism UniProt Comment Textmining
Pseudomonas putida
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Substrates and Products (Substrate)

Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
2-fluorobenzaldehyde carboligation Pseudomonas putida (R)-1,2-Bis-(2-fluoro-phenyl)-2-hydroxy-ethanone 68% yield and more than 99% enantiomeric excess of the (R)-enantiomer ?
2-furaldehyde carboligation Pseudomonas putida (R)-1,2-di-furan-2-yl-2-hydroxy-ethanone 62% yield and 94% enantiomeric excess of the (R)-enantiomer ?
3-methoxybenzaldehyde carboligation Pseudomonas putida (R)-2-Hydroxy-1,2-bis-(3-methoxy-phenyl)-ethanone 18% yield and more than 99% enantiomeric excess of the (R)-enantiomer ?
4-bromobenzaldehyde carboligation Pseudomonas putida (R)-1,2-bis-(4-bromo-phenyl)-2-hydroxy-ethanone 13% yield and more than 99% enantiomeric excess of the (R)-enantiomer ?
4-chlorobenzaldehyde carboligation Pseudomonas putida (R)-1,2-bis-(4-chloro-phenyl)-2-hydroxy-ethanone 17% yield and more than 99% enantiomeric excess of the (R)-enantiomer ?
4-fluorobenzaldehyde carboligation Pseudomonas putida (R)-1,2-Bis-(4-fluoro-phenyl)-2-hydroxy-ethanone 25% yield and more than 99% enantiomeric excess of the (R)-enantiomer ?
4-methoxybenzaldehyde carboligation Pseudomonas putida (R)-2-Hydroxy-1,2-bis-(4-methoxy-phenyl)-ethanone 12% yield and more than 99% enantiomeric excess of the (R)-enantiomer ?
4-methylbenzaldehyde carboligation Pseudomonas putida (R)-2-Hydroxy-1,2-di-p-tolyl-ethanone 69% yield and more than 99% enantiomeric excess of the (R)-enantiomer ?
5-methyl-furan-2-carbaldehyde carboligation Pseudomonas putida (R)-2-Hydroxy-1,2-bis-(5-methyl-furan-2-yl)-ethanone 50% yield and 96% enantiomeric excess of the (R)-enantiomer ?
benzaldehyde + benzaldehyde carboligation Pseudomonas putida (R)-benzoin 70% yield and more than 99% enantiomeric excess of the (R)-enantiomer ?
pyridine-2-carbaldehyde carboligation Pseudomonas putida (R)-2-Hydroxy-1,2-di-pyridin-2-yl-ethanone 70% yield and 94% enantiomeric excess of the (R)-enantiomer ?
thiophene-2-carbaldehyde carboligation Pseudomonas putida (S)-2-Hydroxy-1,2-di-thiophen-2-yl-ethanone 65% yield and 95% enantiomeric excess of the (R)-enantiomer ?