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Literature summary for 3.5.1.36 extracted from
- 5-Hydroxy-N-Methylpyroglutamate synthase. Evidence for an alpha-ketoglutaryl enzyme intermediate from partitioning studies (1971), J. Biol. Chem., 246, 6803-6806.
KM Value [mM]
| KM Value [mM] | KM Value Maximum [mM] | Substrate | Comment | Organism | Structure |
|---|---|---|---|---|---|
| 0.0026 | - |
propyl alpha-ketoglutarate | - |
Pseudomonas sp. |  |
| 0.0045 | - |
ethyl alpha-ketoglutarate | - |
Pseudomonas sp. | |
| 0.0048 | - |
benzyl alpha-ketoglutarate | - |
Pseudomonas sp. | |
Natural Substrates/ Products (Substrates)
| Natural Substrates | Organism | Comment (Nat. Sub.) | Natural Products | Comment (Nat. Pro.) | Rev. | Reac. |
|---|---|---|---|---|---|---|
| 2-oxopentanedioic acid 5-benzyl ester + H2O | Pseudomonas sp. | - |
2-oxoglutarate + benzyl alcohol | - |
? | |
| 2-oxopentanedioic acid 5-benzyl ester + H2O | Pseudomonas sp. MA / M.A. / ATCC 23819 | - |
2-oxoglutarate + benzyl alcohol | - |
? | |
| 2-oxopentanedioic acid 5-ethyl ester + H2O | Pseudomonas sp. | - |
2-oxoglutarate + ethanol | - |
? | |
| 2-oxopentanedioic acid 5-ethyl ester + H2O | Pseudomonas sp. MA / M.A. / ATCC 23819 | - |
2-oxoglutarate + ethanol | - |
? | |
| 2-oxopentanedioic acid 5-propyl ester + H2O | Pseudomonas sp. | - |
2-oxoglutarate + propanol | - |
? | |
| 2-oxopentanedioic acid 5-propyl ester + H2O | Pseudomonas sp. MA / M.A. / ATCC 23819 | - |
2-oxoglutarate + propanol | - |
? | |
Organism
| Organism | UniProt | Comment | Textmining |
|---|---|---|---|
| Pseudomonas sp. | - |
- |
- |
| Pseudomonas sp. MA / M.A. / ATCC 23819 | - |
- |
- |
Substrates and Products (Substrate)
| Substrates | Comment Substrates | Organism | Products | Comment (Products) | Rev. | Reac. |
|---|---|---|---|---|---|---|
| 2-oxopentanedioic acid 5-benzyl ester + H2O | - |
Pseudomonas sp. | 2-oxoglutarate + benzyl alcohol | - |
? | |
| 2-oxopentanedioic acid 5-benzyl ester + H2O | - |
Pseudomonas sp. MA / M.A. / ATCC 23819 | 2-oxoglutarate + benzyl alcohol | - |
? | |
| 2-oxopentanedioic acid 5-ethyl ester + H2O | - |
Pseudomonas sp. | 2-oxoglutarate + ethanol | - |
? | |
| 2-oxopentanedioic acid 5-ethyl ester + H2O | - |
Pseudomonas sp. MA / M.A. / ATCC 23819 | 2-oxoglutarate + ethanol | - |
? | |
| 2-oxopentanedioic acid 5-propyl ester + H2O | - |
Pseudomonas sp. | 2-oxoglutarate + propanol | - |
? | |
| 2-oxopentanedioic acid 5-propyl ester + H2O | - |
Pseudomonas sp. MA / M.A. / ATCC 23819 | 2-oxoglutarate + propanol | - |
? | |
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