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Literature summary for 3.1.3.2 extracted from

  • van Herk, T.; Hartog, A.F.; van der Burg, A.M.; Wever, R.
    Regioselective phosphorylation of carbohydrates and various alcohols by bacterial acid phosphatases; probing the substrate specificity of the enzyme from Shigella flexneri (2005), Adv. Synth. Catal., 347, 1155-1162.
No PubMed abstract available
Search for more literature for 3.1.3.2

Application

Application Comment Organism
synthesis the enzyme is useful in preparative dephosphorylation of compounds, in preparative phosphorylation of glucose and related compounds, and in the phosphorylation of structurally different alcoholic substrates with diphosphate as cheap phosphate donor Salmonella enterica
synthesis the enzyme is useful in preparative dephosphorylation of compounds, in preparative phosphorylation of glucose and related compounds, and in the phosphorylation of structurally different alcoholic substrates with diphosphate as cheap phosphate donor Shigella flexneri

Organism

Organism UniProt Comment Textmining
Salmonella enterica
-
 bifunctional class A2 enzyme
-
Shigella flexneri
-
 bifunctional class A1 enzyme
-

Reaction

Reaction Comment Organism Reaction ID
a phosphate monoester + H2O = an alcohol + phosphate regioselective and stereospecific phosphorylation of diverse substrates by the acid phosphatase from Shigella flexneri and Salmonella enterica Salmonella enterica
a
a phosphate monoester + H2O = an alcohol + phosphate regioselective and stereospecific phosphorylation of diverse substrates by the acid phosphatase from Shigella flexneri and Salmonella enterica Shigella flexneri
a

Substrates and Products (Substrate)

Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
additional information substrate specificity, the enzyme dephosphorylates and also phosphorylates various cyclic and non-cyclic substrates, linear alcohols, and cyclic or aromatic alcohols, in a regioselective and stereospecific manner, overview Salmonella enterica ?
-
 ?
additional information substrate specificity, the enzyme dephosphorylates and also phosphorylates various cyclic and non-cyclic substrates, linear alcohols, and cyclic or aromatic alcohols, in a regioselective and stereospecific manner, the enzyme prefers primary alcohol functions above the a secondary, overview Shigella flexneri ?
-
 ?

Synonyms

Synonyms Comment Organism
non-specific acid phosphatase
-
 Salmonella enterica
non-specific acid phosphatase
-
 Shigella flexneri
PhoN-Se
-
 Salmonella enterica
PhoN-Sf
-
 Shigella flexneri

Temperature Optimum [°C]

Temperature Optimum [°C] Temperature Optimum Maximum [°C] Comment Organism
30
-
 assay at Salmonella enterica
30
-
 assay at Shigella flexneri

pH Optimum

pH Optimum Minimum pH Optimum Maximum Comment Organism
4 5.3 assay at Salmonella enterica
4 5.3 assay at Shigella flexneri