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Literature summary for 3.1.2.6 extracted from

  • Danford, J.J.; Arif, A.M.; Berreau, L.M.
    Thioester hydrolysis promoted by a mononuclear zinc complex (2010), Inorg. Chem., 49, 778-780.
    View publication on PubMed

Activating Compound

Activating Compound Comment Organism Structure
additional information the mononuclear zinc complex [(bpta)Zn](ClO4)2 x 0.5 H2O promotes the hydrolysis of thioester when dissolved in CH3CN:H2O (50:50 buffered at pH 9.0). This reaction results in the formation of a mixture of CD3SH and a zinc thiolate complex, the latter of which can be protonated to generate additional CD3SH Homo sapiens

Metals/Ions

Metals/Ions Comment Organism Structure
Zinc the mononuclear zinc complex [(bpta)Zn](ClO4)2 x 0.5 H2O promotes the hydrolysis of thioester when dissolved in CH3CN:H2O (50:50 buffered at pH 9.0). This reaction results in the formation of a mixture of CD3SH and a zinc thiolate complex, the latter of which can be protonated to generate additional CD3SH Homo sapiens

Organism

Organism UniProt Comment Textmining
Homo sapiens
-
-
-

Substrates and Products (Substrate)

Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
S-methyl hydroxy(phenyl)ethanethioate + H2O thioester hydrolysis promoted by a mononuclear zinc complex Homo sapiens methanethiol + hydroxy(phenyl)acetic acid
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Synonyms

Synonyms Comment Organism
GlxII
-
Homo sapiens
glyoxalase II
-
Homo sapiens