Any feedback?
Please rate this page
(literature.php)
(0/150)

BRENDA support

Literature summary for 3.1.1.73 extracted from

  • Hatzakis, N.S.; Daphnomili, D.; Smonou, I.
    Ferulic acid esterase from Humicola Insolens catalyzes enantioselective transesterification of secondary alcohols (2003), J. Mol. Catal. B, 21, 309-311.
No PubMed abstract available

Application

Application Comment Organism
synthesis potential for the production of ferulic acid as antioxidant, food preservative, anti-inflammatory and antitumor agent, photoprotectant or flavor precursor Humicola insolens

Localization

Localization Comment Organism GeneOntology No. Textmining
extracellular
-
Humicola insolens
-
-

Natural Substrates/ Products (Substrates)

Natural Substrates Organism Comment (Nat. Sub.) Natural Products Comment (Nat. Pro.) Rev. Reac.
feruloyl polysaccharide + H2O Humicola insolens involved in the degradation of plant cell wall material, breaks ferulic acid cross-links between cell wall components ferulic acid + ? monomeric and 5,5’ dimeric forms released from insoluble plant cell wall material ?

Organism

Organism UniProt Comment Textmining
Humicola insolens
-
-
-

Substrates and Products (Substrate)

Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
1-(1,1'-biphenyl)-4-yl-1-ethanol + vinyl acetate transesterification, 17% conversion with a 30-fold excess of vinyl acetate, high enantioselectivity with R enantiopreference Humicola insolens ?
-
?
1-(3-methylphenyl)-1-ethanol + vinyl acetate transesterification, 52% conversion with a 30fold excess of vinyl acetate, high enantioselectivity with R enantiopreference Humicola insolens ?
-
?
1-(4-isopropylphenyl)-1-ethanol + vinyl acetate transesterification, 7% conversion with a 30fold excess of vinyl acetate, high enantioselectivity with R enantiopreference Humicola insolens ?
-
?
1-(4-methoxyphenyl)-1-ethanol + vinyl acetate transesterification, 18% conversion with a 30fold excess of vinyl acetate, high enantioselectivity with R enantiopreference Humicola insolens ?
-
?
1-(4-pyridinyl)-1-ethanol + vinyl acetate transesterification, 50% conversion with a 30fold excess of vinyl acetate, high enantioselectivity with R enantiopreference Humicola insolens 1-pyridin-4-ylethylacetate + prop-2-en-1-ol
-
?
1-phenyl-1-ethanol + vinyl acetate transesterification, 23% conversion with a 30fold excess of vinyl acetate, high enantioselectivity with R enantiopreference Humicola insolens ?
-
?
1-phenyl-1-propanol + vinyl acetate transesterification, 25% conversion with a 30fold excess of vinyl acetate, high enantioselectivity with R enantiopreference Humicola insolens ?
-
?
feruloyl polysaccharide + H2O involved in the degradation of plant cell wall material, breaks ferulic acid cross-links between cell wall components Humicola insolens ferulic acid + ? monomeric and 5,5’ dimeric forms released from insoluble plant cell wall material ?