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Literature summary for 3.1.1.3 extracted from

  • Hirohara, H.; Nishizawa, M.
    Biochemical synthesis of several chemical insecticide intermediates and mechanism of action of relevant enzymes (1998), Biosci. Biotechnol. Biochem., 62, 1-9.
    View publication on PubMed

Application

Application Comment Organism
synthesis production of (S)-acetic acid 2-methyl-4-oxo-3-prop-2-ynyl-cyclopent-2-enyl ester, which is used as an intermediate in the synthesis of pyrethroids, which are used as insecticides. They show excellent insecticidal activities and a low toxicity in mammals. Arthrobacter sp.

Organism

Organism UniProt Comment Textmining
Arthrobacter sp.
-
-
-

Substrates and Products (Substrate)

Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
(S,R)-acetic acid 2-methyl-4-oxo-3-prop-2-ynyl-cyclopent-2-enyl ester + H2O
-
Arthrobacter sp. (R)-4-hydroxy-3-methyl-2-prop-2-ynyl-cyclopent-2-enone + (S)-acetic acid 2-methyl-4-oxo-3-prop-2-ynyl-cyclopent-2-enyl ester + acetate
-
?

Temperature Optimum [°C]

Temperature Optimum [°C] Temperature Optimum Maximum [°C] Comment Organism
40
-
-
Arthrobacter sp.

pH Optimum

pH Optimum Minimum pH Optimum Maximum Comment Organism
7
-
-
Arthrobacter sp.