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Literature summary for 2.6.1.109 extracted from

  • Leone, S.; Molinaro, A.; De Castro, C.; Baier, A.; Nazarenko, E.; Lanzetta, R.; Parrilli, M.
    Absolute configuration of 8-amino-3,8-dideoxyoct-2-ulosonic acid, the chemical hallmark of lipopolysaccharides of the genus Shewanella (2007), J. Nat. Prod., 70, 1624-1627.
    View publication on PubMed

Natural Substrates/ Products (Substrates)

Natural Substrates Organism Comment (Nat. Sub.) Natural Products Comment (Nat. Pro.) Rev. Reac.
8-dehydro-3-deoxy-D-manno-octulosonic acid + L-glutamate Shewanella japonica i.e. Kdo 8-amino-3,8-dideoxy-D-manno-octulosonic acid + 2-oxoglutarate i.e. Kdo8N ?
8-dehydro-3-deoxy-D-manno-octulosonic acid + L-glutamate Shewanella japonica KMM 3772 i.e. Kdo 8-amino-3,8-dideoxy-D-manno-octulosonic acid + 2-oxoglutarate i.e. Kdo8N ?

Organism

Organism UniProt Comment Textmining
Shewanella japonica
-
-
-
Shewanella japonica KMM 3772
-
-
-

Substrates and Products (Substrate)

Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
8-dehydro-3-deoxy-D-manno-octulosonic acid + L-glutamate i.e. Kdo Shewanella japonica 8-amino-3,8-dideoxy-D-manno-octulosonic acid + 2-oxoglutarate i.e. Kdo8N ?
8-dehydro-3-deoxy-D-manno-octulosonic acid + L-glutamate i.e. Kdo Shewanella japonica 8-amino-3,8-dideoxy-D-manno-octulosonic acid + 2-oxoglutarate i.e. Kdo8N, the D-manno-configuration of the monosaccharide is determined by Mosher ester method, absolute configuration is 4R,5R,6R,7R, NMR spectrometry, overview ?
8-dehydro-3-deoxy-D-manno-octulosonic acid + L-glutamate i.e. Kdo Shewanella japonica KMM 3772 8-amino-3,8-dideoxy-D-manno-octulosonic acid + 2-oxoglutarate i.e. Kdo8N ?
8-dehydro-3-deoxy-D-manno-octulosonic acid + L-glutamate i.e. Kdo Shewanella japonica KMM 3772 8-amino-3,8-dideoxy-D-manno-octulosonic acid + 2-oxoglutarate i.e. Kdo8N, the D-manno-configuration of the monosaccharide is determined by Mosher ester method, absolute configuration is 4R,5R,6R,7R, NMR spectrometry, overview ?

General Information

General Information Comment Organism
metabolism typical LPS architecture is organized into three distinct regions, termed lipid A, core, and O-chain, respectively, each characterized by its own structure, biosynthesis, and function. The connection between the lipid A and the core oligosaccharide is held by a characteristic monosaccharide, 3-deoxy-D-manno-oct-2-ulosonic acid, i.e. Kdo Shewanella japonica