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Literature summary for 1.4.3.2 extracted from

  • Kamio, M.; Ko, K.C.; Zheng, S.; Wang, B.; Collins, S.L.; Gadda, G.; Tai, P.C.; Derby, C.D.
    The chemistry of escapin: identification and quantification of the components in the complex mixture generated by an L-amino acid oxidase in the defensive secretion of the sea snail Aplysia californica (2009), Chemistry, 15, 1597-1603.
    View publication on PubMed

KM Value [mM]

KM Value [mM] KM Value Maximum [mM] Substrate Comment Organism Structure
additional information
-
additional information kinetics Aplysia californica

Localization

Localization Comment Organism GeneOntology No. Textmining
extracellular defensive ink Aplysia californica
-
-

Natural Substrates/ Products (Substrates)

Natural Substrates Organism Comment (Nat. Sub.) Natural Products Comment (Nat. Pro.) Rev. Reac.
L-Lys + H2O + O2 Aplysia californica
-
6-amino-2-oxohexanoic acid + NH3 + H2O2
-
?
L-Lys + H2O + O2 Aplysia californica Cooper 1863
-
6-amino-2-oxohexanoic acid + NH3 + H2O2
-
?

Organism

Organism UniProt Comment Textmining
Aplysia californica Q6IWZ0 collected in California
-
Aplysia californica Cooper 1863 Q6IWZ0 collected in California
-

Source Tissue

Source Tissue Comment Organism Textmining
ink
-
Aplysia californica
-

Substrates and Products (Substrate)

Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
L-Lys + H2O + O2
-
Aplysia californica 6-amino-2-oxohexanoic acid + NH3 + H2O2
-
?
L-Lys + H2O + O2
-
Aplysia californica 6-amino-2-oxohexanoic acid + NH3 + H2O2 the enzymatic reaction likely forms an equilibrium mixture containing the linear form 6-amino-2-oxohexanoic acid, the cyclic imine D1-piperidine-2-carboxylic acid, the cyclic enamine D2-piperidine-2-carboxylic acid, possibly the linear enol 6-amino-2-hydroxy-hex-2-enoic acid, the alpha-dihydroxyacid 6-amino-2,2-dihydroxy-hexanoic acid, and the cyclic aminol 2-hydroxy-piperidine-2-carboxylic acid, identification and quantification by mass spectrometry and NMR, overview ?
L-Lys + H2O + O2
-
Aplysia californica Cooper 1863 6-amino-2-oxohexanoic acid + NH3 + H2O2
-
?
L-Lys + H2O + O2
-
Aplysia californica Cooper 1863 6-amino-2-oxohexanoic acid + NH3 + H2O2 the enzymatic reaction likely forms an equilibrium mixture containing the linear form 6-amino-2-oxohexanoic acid, the cyclic imine D1-piperidine-2-carboxylic acid, the cyclic enamine D2-piperidine-2-carboxylic acid, possibly the linear enol 6-amino-2-hydroxy-hex-2-enoic acid, the alpha-dihydroxyacid 6-amino-2,2-dihydroxy-hexanoic acid, and the cyclic aminol 2-hydroxy-piperidine-2-carboxylic acid, identification and quantification by mass spectrometry and NMR, overview ?
additional information effect of pH on conversion of escapin intermediates to escapin end products, overview Aplysia californica ?
-
?
additional information effect of pH on conversion of escapin intermediates to escapin end products, overview Aplysia californica Cooper 1863 ?
-
?

Synonyms

Synonyms Comment Organism
escapin
-
Aplysia californica
LAAO
-
Aplysia californica

Temperature Optimum [°C]

Temperature Optimum [°C] Temperature Optimum Maximum [°C] Comment Organism
25
-
assay at Aplysia californica

pH Range

pH Minimum pH Maximum Comment Organism
4.5 8.5 pH-profile, overview Aplysia californica