Literature summary for 1.14.99.56 extracted from

Beeson, W.; Phillips, C.; Cate, J.; Marletta, M.
Oxidative cleavage of cellulose by fungal copper-dependent polysaccharide monooxygenases (2012), J. Am. Chem. Soc., 134, 890-892.

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Organism

Organism	UniProt	Comment	Textmining
Neurospora crassa	Q7RWN7	-	-
Neurospora crassa DSM 1257	Q7RWN7	-	-

Substrates and Products (Substrate)

Substrates	Comment Substrates	Organism	Products	Comment (Products)	Rev.	Reac.
additional information	the enzyme inserts oxygen at the 4-position. After oxygen insertion, the glycosidic bond is destabilized and likely broken by an elimination reaction, which may be catalyzed by the PMO or occur spontaneously. This elimination is irreversible because the carbon on the reducing or nonreducing end has been oxidized	Neurospora crassa	?	-	?
additional information	the enzyme inserts oxygen at the 4-position. After oxygen insertion, the glycosidic bond is destabilized and likely broken by an elimination reaction, which may be catalyzed by the PMO or occur spontaneously. This elimination is irreversible because the carbon on the reducing or nonreducing end has been oxidized	Neurospora crassa DSM 1257	?	-	?
phosphoric acid swollen cellulose + ascorbate + O2	-	Neurospora crassa	? + dehydroascorbate + H2O	the nonreducing end product is a 4-ketoaldose	?
phosphoric acid swollen cellulose + ascorbate + O2	-	Neurospora crassa DSM 1257	? + dehydroascorbate + H2O	the nonreducing end product is a 4-ketoaldose	?

Synonyms

Synonyms	Comment	Organism
gh61-5	-	Neurospora crassa
NCU08760	-	Neurospora crassa

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Release 2023.1 (January 2023)