Any feedback?
Please rate this page
(literature.php)
(0/150)

BRENDA support

Literature summary for 1.14.20.11 extracted from

  • Huang, J.L.; Tang, Y.; Yu, C.P.; Sanyal, D.; Jia, X.; Liu, X.; Guo, Y.; Chang, W.C.
    Mechanistic investigation of oxidative decarboxylation catalyzed by two iron(II)- and 2-oxoglutarate-dependent enzymes (2018), Biochemistry, 57, 1838-1841 .
    View publication on PubMed
Search for more literature for 1.14.20.11

Organism

Organism UniProt Comment Textmining
Fischerella ambigua V5TD18
-
-
Fischerella ambigua UTEX 1903 V5TD18
-
-

Substrates and Products (Substrate)

Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
(2S)-3-(1H-indol-3-yl)-2-isocyanopropanoate + 2-oxoglutarate + O2
-
 Fischerella ambigua 3-[(Z)-2-isocyanoethenyl]-1H-indole + succinate + 2 CO2 + H2O
-
 ?
(2S)-3-(1H-indol-3-yl)-2-isocyanopropanoate + 2-oxoglutarate + O2
-
 Fischerella ambigua UTEX 1903 3-[(Z)-2-isocyanoethenyl]-1H-indole + succinate + 2 CO2 + H2O
-
 ?
additional information enzyme initiates stereoselective olefination via a benzylic C-H bond activation by an Fe(IV)-oxo intermediate, and the reaction likely proceeds through a radical- or carbocation-induced decarboxylation to complete C=C bond installation Fischerella ambigua ?
-
 ?
additional information enzyme initiates stereoselective olefination via a benzylic C-H bond activation by an Fe(IV)-oxo intermediate, and the reaction likely proceeds through a radical- or carbocation-induced decarboxylation to complete C=C bond installation Fischerella ambigua UTEX 1903 ?
-
 ?

Synonyms

Synonyms Comment Organism
ambI3
-
 Fischerella ambigua