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Literature summary for 1.14.14.59 extracted from

  • Richter, A.; Schaff, C.; Zhang, Z.; Lipka, A.; Tian, F.; Koellner, T.; Schnee, C.; Preiss, S.; Irmisch, S.; Jander, G.; Boland, W.; Gershenzon, J.; Buckler, E.; Degenhardt, J.
    Characterization of biosynthetic pathways for the production of the volatile homoterpenes DMNT and TMTT in Zea mays (2016), Plant Cell, 28, 2651-2665 .
    View publication on PubMedView publication on EuropePMC

Cloned(Commentary)

Cloned (Comment) Organism
expression in Saccharomyces cerevisiae Zea mays

KM Value [mM]

KM Value [mM] KM Value Maximum [mM] Substrate Comment Organism Structure
0.0142
-
(3S,6E)-nerolidol pH 6.8, 30°C Zea mays

Organism

Organism UniProt Comment Textmining
Zea mays B6ST66 enzyme catalyzes reactions of EC 1.14.14.58 and of EC 1.14.14.59
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Substrates and Products (Substrate)

Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
(3S,6E)-nerolidol + [reduced NADPH-hemoprotein reductase] + O2
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Zea mays (3E)-4,8-dimethylnona-1,3,7-triene + [oxidized NADPH-hemoprotein reductase] + but-3-en-2-one + 2 H2O
-
?
additional information no substrate: linalool Zea mays ?
-
?

Synonyms

Synonyms Comment Organism
CYP92C5
-
Zea mays

Cofactor

Cofactor Comment Organism Structure
cytochrome P450
-
Zea mays

Expression

Organism Comment Expression
Zea mays low transcript levels in undamaged leaves, expression is strongly induced in response to simulated herbivory additional information

General Information

General Information Comment Organism
physiological function gene disruption of CYP92C5 results in loss of (3E)-4,8-dimethylnona-1,3,7-triene production and reduced levels of (3E,7E)-4,8,12-trimethyltrideca-1,3,7,11-tetraene after simulated herbivory. In planta (3E)-4,8-dimethylnona-1,3,7-triene is primarily produced by isoform CYP92C5, whereas the majority of (3E,7E)-4,8,12-trimethyltrideca-1,3,7,11-tetraene is produced by cytochrome P450 monooxygenase, CYP92C6 Zea mays