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Literature summary for 1.14.13.22 extracted from

  • Pasta, P.; Carrea, G.; Holland, H.L.; Dallavalle, S.
    Synthesis of chiral benzyl alkyl sulfoxides by cyclohexanone monooxygenase from Acinetobacter NCIB 9871 (1995), Tetrahedron, 6, 933-936.
No PubMed abstract available

Organism

Organism UniProt Comment Textmining
Acinetobacter sp.
-
NCIB 9871
-

Reaction

Reaction Comment Organism Reaction ID
cyclohexanone + NADPH + H+ + O2 = hexano-6-lactone + NADP+ + H2O stereochemistry and enantioselectivity of the oxidation reaction depends strongly on the structure and stereochemistry of the substrates Acinetobacter sp.

Substrates and Products (Substrate)

Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
2-phenylethyl methyl sulfide + NADPH + O2
-
Acinetobacter sp. 2-phenylethyl methyl sulfoxide
-
?
2-phenylpropyl methyl sulfide + NADPH + O2
-
Acinetobacter sp. 2-phenylpropyl methyl sulfoxide
-
?
cyclohexanone + NADPH + O2
-
Acinetobacter sp. 6-hexanolide + NADP+ + H2O
-
?
additional information high enantioselectivity in oxidation of sulfides Acinetobacter sp. ?
-
?
additional information active with benzyl alkyl sulfides with alkyl groups from methyl to hexyl and para-alkylbenzyl groups from methyl to butyl Acinetobacter sp. ?
-
?