Any feedback?
Please rate this page
(literature.php)
(0/150)

BRENDA support

Literature summary for 1.14.13.208 extracted from

  • Rokob, T.
    Pathways for arene oxidation in non-heme diiron enzymes lessons from computational studies on benzoyl coenzyme A epoxidase (2016), J. Am. Chem. Soc., 138, 14623-14638 .
    View publication on PubMed
Search for more literature for 1.14.13.208

Metals/Ions

Metals/Ions Comment Organism Structure
Fe2+ a non-heme diiron enzyme Aromatoleum evansii

Natural Substrates/ Products (Substrates)

Natural Substrates Organism Comment (Nat. Sub.) Natural Products Comment (Nat. Pro.) Rev. Reac.
benzoyl-CoA + NADPH + H+ + O2 Aromatoleum evansii
-
 2,3-epoxy-2,3-dihydrobenzoyl-CoA + NADP+ + H2O
-
 ?
benzoyl-CoA + NADPH + H+ + O2 Aromatoleum evansii KB 740
-
 2,3-epoxy-2,3-dihydrobenzoyl-CoA + NADP+ + H2O
-
 ?
additional information Aromatoleum evansii benzoyl-CoA epoxidase is a dinuclear iron enzyme that catalyzes the epoxidation reaction of the aromatic ring of benzoyl-CoA with chemo-, regio- and stereo-selectivity ?
-
 ?
additional information Aromatoleum evansii KB 740 benzoyl-CoA epoxidase is a dinuclear iron enzyme that catalyzes the epoxidation reaction of the aromatic ring of benzoyl-CoA with chemo-, regio- and stereo-selectivity ?
-
 ?

Organism

Organism UniProt Comment Textmining
Aromatoleum evansii
-
-
-
Aromatoleum evansii KB 740
-
-
-

Reaction

Reaction Comment Organism Reaction ID
benzoyl-CoA + NADPH + H+ + O2 = 2,3-epoxy-2,3-dihydrobenzoyl-CoA + NADP+ + H2O molecular reaction mechanism analysis, different pathways are possible, detailed overview Aromatoleum evansii
a

Substrates and Products (Substrate)

Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
benzoyl-CoA + NADPH + H+ + O2
-
 Aromatoleum evansii 2,3-epoxy-2,3-dihydrobenzoyl-CoA + NADP+ + H2O
-
 ?
benzoyl-CoA + NADPH + H+ + O2
-
 Aromatoleum evansii KB 740 2,3-epoxy-2,3-dihydrobenzoyl-CoA + NADP+ + H2O
-
 ?
additional information benzoyl-CoA epoxidase is a dinuclear iron enzyme that catalyzes the epoxidation reaction of the aromatic ring of benzoyl-CoA with chemo-, regio- and stereo-selectivity Aromatoleum evansii ?
-
 ?
additional information benzoyl-CoA epoxidase is a dinuclear iron enzyme that catalyzes the epoxidation reaction of the aromatic ring of benzoyl-CoA with chemo-, regio- and stereo-selectivity Aromatoleum evansii KB 740 ?
-
 ?

Synonyms

Synonyms Comment Organism
benzoyl coenzyme A epoxidase
-
 Aromatoleum evansii
benzoyl-CoA epoxidase
-
 Aromatoleum evansii
BoxB
-
 Aromatoleum evansii

General Information

General Information Comment Organism
additional information usage of PDB ID 3PM5 for enzyme structure modeling and simulation, quantum mechanics/molecular mechanics calculations, overview. Four general pathways for oxidizing aromatic rings are determined Aromatoleum evansii