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Literature summary for 1.13.11.54 extracted from

  • Valdez, C.; Gallup, N.; Alexandrova, A.
    Co2+ acireductone dioxygenase Fe2+ mechanism, Ni2+ mechanism, or something else? (2014), Chem. Phys. Lett., 604, 77-82 .
No PubMed abstract available

Crystallization (Commentary)

Crystallization (Comment) Organism
quantum-classical dynamics simulations with Co2+ bound. Both Fe2+-like (reaction of EC 1.13.11.54) and Ni2+-like (reaction of EC 1.13.11.53) routes are accessible to Co2+-ARD. with low spin Co2+, the reaction exclusively follows the Fe2+-dependent pathways, producing alpha-keto acid precursor of methionine and formate, while the high spin Co2+ path contains a bifurcation in the pathway that follows along both the Fe2+-dependent pathway and Ni2+-dependent pathway that produces methylthiopropionate, carbon monoxide and formate Klebsiella oxytoca

Metals/Ions

Metals/Ions Comment Organism Structure
Co2+ quantum-classical dynamics simulations with Co2+ bound. both Fe2+-like (reaction of EC 1.13.11.54) and Ni2+-like (reaction of EC 1.13.11.53) routes are accessible to Co2+-ARD, but the mechanism involves a bifurcating transition state, and so the exact product distribution is determined by the reaction dynamics Klebsiella oxytoca

Organism

Organism UniProt Comment Textmining
Klebsiella oxytoca Q9ZFE7
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Synonyms

Synonyms Comment Organism
MtnD
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Klebsiella oxytoca