Organism | UniProt | Comment | Textmining |
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synthetic construct | - |
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General Information | Comment | Organism |
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metabolism | compounds TpMesMFla (TpMes = hydrotris(3-mesityl)pyrazolylborate, M = Mn, Fe, Co, Ni, Zn, Fla = 3-hydroxyflavonolate) as models for 2,4-quercetin dioxygenase. The structures differ in the degree of delocalization in the chelate ring formed through the binding of the two O donors of the flavonolate to the metal center, the resulting trend (Zn/Fe > Co > Mn > Ni) is, not in line with the one that found when investigating the redox properties of the complexes by cyclic voltammetry (Zn > Fe > Ni > Co > Mn). The complexes exhibit exceptionally well-behaved quasi-reversible redox transitions. After the O2 reaction, salicylic acid is one of the products | synthetic construct |