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Literature summary for 1.11.2.3 extracted from

  • Fuchs, C.; Schwab, W.
    Epoxidation, hydroxylation and aromatization is catalyzed by a peroxygenase from Solanum lycopersicum (2013), J. Mol. Catal. B, 96, 52-60.
No PubMed abstract available

Cloned(Commentary)

Cloned (Comment) Organism
expression in Saccharomyces cervisiae Solanum lycopersicum

KM Value [mM]

KM Value [mM] KM Value Maximum [mM] Substrate Comment Organism Structure
0.071
-
oleic acid pH 6.0, 40°C Solanum lycopersicum
0.078
-
linoleic acid pH 6.0, 40°C Solanum lycopersicum
0.815
-
trans-10,cis-12-linoleic acid pH 6.0, 40°C Solanum lycopersicum

Molecular Weight [Da]

Molecular Weight [Da] Molecular Weight Maximum [Da] Comment Organism
27900
-
x * 27900, calculated, x * 28000, SDS-PAGE Solanum lycopersicum
28000
-
x * 27900, calculated, x * 28000, SDS-PAGE Solanum lycopersicum

Organism

Organism UniProt Comment Textmining
Solanum lycopersicum
-
-
-

Substrates and Products (Substrate)

Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
(+)-(R)-limonene + H2O2
-
Solanum lycopersicum (R)-limonene trans-1,2-epoxide 97% of products ?
(-)-(S)-limonene + H2O2
-
Solanum lycopersicum (S)-limonene cis-1,2-epoxide 88% of products ?
alpha-terpinene + H2O2
-
Solanum lycopersicum cis-1,4-dihydroxy-p-menth-2-ene
-
?
gamma-terpinene + H2O2
-
Solanum lycopersicum p-cymene in this reaction, hydroperoxide serves as hydrogen acceptor rather than an oxygen donor ?
linoleic acid + H2O2
-
Solanum lycopersicum 15,16-epoxy-9,12-octadecadienoic acid + H2O 25% yield ?
additional information no substrate: geraniol Solanum lycopersicum ?
-
?
nerol + H2O2
-
Solanum lycopersicum nerol-2,3-epoxide sole product ?
oleic acid + H2O2
-
Solanum lycopersicum 9,10-epoxyoctadecanoic acid 15% yield ?
trans-10,cis-12-linoleic acid + H2O2
-
Solanum lycopersicum 12,13-epoxy-10-octadecenoic acid epoxidation occurs only at cis-double bond ?

Subunits

Subunits Comment Organism
? x * 27900, calculated, x * 28000, SDS-PAGE Solanum lycopersicum

Temperature Optimum [°C]

Temperature Optimum [°C] Temperature Optimum Maximum [°C] Comment Organism
40
-
-
Solanum lycopersicum

pH Optimum

pH Optimum Minimum pH Optimum Maximum Comment Organism
6
-
-
Solanum lycopersicum

Cofactor

Cofactor Comment Organism Structure
additional information no cofactors required Solanum lycopersicum