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Literature summary for 1.11.2.3 extracted from

  • Piazza, G.J.; Foglia, T.A.
    One-pot synthesis of fatty acid epoxides from triacylglycerols using enzymes present in oat seeds (2006), J. Am. Oil Chem. Soc., 83, 1021-1025.
    View publication on PubMed

Metals/Ions

Metals/Ions Comment Organism Structure
additional information peroxygenase activity is not stimulated by Ca2+ Avena sativa

Natural Substrates/ Products (Substrates)

Natural Substrates Organism Comment (Nat. Sub.) Natural Products Comment (Nat. Pro.) Rev. Reac.
(9Z,12Z,15Z)-octadeca-9,12,15-trienoic acid + tert-butyl hydroperoxide Avena sativa
-
(12Z,15Z)-9,10-epoxyoctadeca-12,15-dienoic aicd + (9Z,12Z)-15,16-epoxy-9,12-octadecadienoic acid + ?
-
?
2 linolenic acid + 3 tert-butyl hydroperoxide Avena sativa
-
(12Z,15Z)-9-epoxyoctadec-12,15-dienoic acid + (12Z)-9,15-diepoxyoctadec-12-enoic acid + 3 tert-butanol
-
?
linoleic acid + tert-butyl hydroperoxide Avena sativa
-
9,10-epoxy-octadecanoic acid + tert-butanol
-
?
additional information Avena sativa the enzyme does not oxidize diacylglycerol and triacylglycerol ?
-
?

Organism

Organism UniProt Comment Textmining
Avena sativa
-
-
-

Source Tissue

Source Tissue Comment Organism Textmining
seed
-
Avena sativa
-

Substrates and Products (Substrate)

Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
(9Z,12Z,15Z)-octadeca-9,12,15-trienoic acid + tert-butyl hydroperoxide
-
Avena sativa (12Z,15Z)-9,10-epoxyoctadeca-12,15-dienoic aicd + (9Z,12Z)-15,16-epoxy-9,12-octadecadienoic acid + ?
-
?
2 linolenic acid + 3 tert-butyl hydroperoxide
-
Avena sativa (12Z,15Z)-9-epoxyoctadec-12,15-dienoic acid + (12Z)-9,15-diepoxyoctadec-12-enoic acid + 3 tert-butanol
-
?
linoleic acid + tert-butyl hydroperoxide
-
Avena sativa 9,10-epoxy-octadecanoic acid + tert-butanol
-
?
additional information the enzyme does not oxidize diacylglycerol and triacylglycerol Avena sativa ?
-
?

Synonyms

Synonyms Comment Organism
plant peroxygenase
-
Avena sativa

pH Optimum

pH Optimum Minimum pH Optimum Maximum Comment Organism
6 7
-
Avena sativa