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Literature summary for 1.11.2.1 extracted from

  • Peter, S.; Karich, A.; Ullrich, R.; Groebe, G.; Scheibner, K.; Hofrichter, M.
    Enzymatic one-pot conversion of cyclohexane into cyclohexanone Comparison of four fungal peroxygenases (2014), J. Mol. Catal. B, 103, 47-51 .
No PubMed abstract available
Search for more literature for 1.11.2.1

KM Value [mM]

KM Value [mM] KM Value Maximum [mM] Substrate Comment Organism Structure
0.397
-
 Cyclohexane at pH 7.0 and 22°C Coprinopsis cinerea
0.994
-
 Cyclohexane at pH 7.0 and 22°C Cyclocybe aegerita
1.844
-
 Cyclohexanol at pH 7.0 and 22°C Marasmius rotula
2.242
-
 Cyclohexane at pH 7.0 and 22°C Marasmius rotula
4.977
-
 Cyclohexanol at pH 7.0 and 22°C Cyclocybe aegerita
6.571
-
 Cyclohexanol at pH 7.0 and 22°C Coprinopsis cinerea

Organism

Organism UniProt Comment Textmining
Coprinopsis cinerea
-
-
-
Cyclocybe aegerita B9W4V6
-
-
Marasmius rotula
-
-
-

Substrates and Products (Substrate)

Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
cyclohexane + H2O2
-
 Coprinopsis cinerea cyclohexanol + H2O
-
 ?
cyclohexane + H2O2
-
 Cyclocybe aegerita cyclohexanol + H2O
-
 ?
cyclohexane + H2O2
-
 Marasmius rotula cyclohexanol + H2O
-
 ?
cyclohexanol + H2O2
-
 Coprinopsis cinerea cyclohexanone + H2O
-
 ?
cyclohexanol + H2O2
-
 Cyclocybe aegerita cyclohexanone + H2O
-
 ?
cyclohexanol + H2O2
-
 Marasmius rotula cyclohexanone + H2O
-
 ?

Synonyms

Synonyms Comment Organism
UPO
-
 Coprinopsis cinerea
UPO
-
 Cyclocybe aegerita
UPO
-
 Marasmius rotula

Turnover Number [1/s]

Turnover Number Minimum [1/s] Turnover Number Maximum [1/s] Substrate Comment Organism Structure
3
-
 Cyclohexanol at pH 7.0 and 22°C Coprinopsis cinerea
5
-
 Cyclohexanol at pH 7.0 and 22°C Cyclocybe aegerita
13
-
 Cyclohexane at pH 7.0 and 22°C Coprinopsis cinerea
31
-
 Cyclohexanol at pH 7.0 and 22°C Marasmius rotula
43
-
 Cyclohexane at pH 7.0 and 22°C Marasmius rotula
72
-
 Cyclohexane at pH 7.0 and 22°C Cyclocybe aegerita

Cofactor

Cofactor Comment Organism Structure
heme
-
 Coprinopsis cinerea
heme
-
 Cyclocybe aegerita
heme
-
 Marasmius rotula

kcat/KM [mM/s]

kcat/KM Value [1/mMs-1] kcat/KM Value Maximum [1/mMs-1] Substrate Comment Organism Structure
0.39
-
 Cyclohexanol at pH 7.0 and 22°C Coprinopsis cinerea
0.97
-
 Cyclohexanol at pH 7.0 and 22°C Cyclocybe aegerita
1.7
-
 Cyclohexanol at pH 7.0 and 22°C Marasmius rotula
3.2
-
 Cyclohexane at pH 7.0 and 22°C Coprinopsis cinerea
43
-
 Cyclohexane at pH 7.0 and 22°C Marasmius rotula
72
-
 Cyclohexane at pH 7.0 and 22°C Cyclocybe aegerita