Literature summary for 1.1.3.47 extracted from

Pickl, M.; Jost, E.; Glueck, S.; Faber, K.
Improved biooxidation of Benzyl alcohols catalyzed by the flavoprotein (5-hydroxymethyl)furfural oxidase in organic solvents (2017), Tetrahedron, 73, 5408-5410 .

No PubMed abstract available

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Application

Application	Comment	Organism
synthesis	biooxidation of benzylic alcohols in the presence of various organic (co)solvents. The enzyme activity decreases at elevated concentrations of water-miscible polar solvents, while the presence of (halogenated) hydrocarbons is tolerated up to 90% (v/v), which leads to drastically improved conversions of up to >99% in case of hexafluorobenzene. This effect is correlated with the improved solubility of O2 in the employed solvents	Methylovorus sp. MP688

Organic Solvent Stability

Organic Solvent	Comment	Organism
hexafluorobenzene	improved conversion of up to 99% in 50-90% , v/v	Methylovorus sp. MP688
additional information	the enzyme activity decreases at elevated concentrations of water-miscible polar solvents, while the presence of (halogenated) hydrocarbons is tolerated up to 90% (v/v)	Methylovorus sp. MP688

Organism

Organism	UniProt	Comment	Textmining
Methylovorus sp. MP688	E4QP00	-	-

Substrates and Products (Substrate)

Substrates	Comment Substrates	Organism	Products	Comment (Products)	Rev.	Reac.
benzyl alcohol + O2	19% conversion	Methylovorus sp. MP688	benzaldehyde + H2O2	-	?

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Release 2023.1 (January 2023)