Ligand 12-oxo-phytodienoic acid

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Basic Ligand Information

Molecular Structure
Picture of 12-oxo-phytodienoic acid (click for magnification)
Molecular Formula
BRENDA Name
InChIKey
C18H28O3
12-oxo-phytodienoic acid
PMTMAFAPLCGXGK-JMTMCXQRSA-N
Synonyms:
(9S,13S)-(15Z)-12-oxophyto-10,15-dienoate, (9S,13S)-12-oxo-(10,15Z)-phytodienoic acid, (9S,13S)-12-oxo-phytodienoic acid, (9S,13S)-12-oxophytodienoate, (9S,13S)-12-oxophytodienoic acid, (9S,13S,15Z)-12-oxophyto-10,15-dienoate, (15Z)-12-oxophyto-10,15-dienoate, 9S,13S-12-oxo-phytodienoic acid, 12-OPDA, 12-oxo-10,15(Z)-phytodienoic acid, 12-oxo-cis-10,15-phytodienoic acid, 12-oxo-cis-phythodienoic acid, 12-oxophytodienoic acid, cis-(+)-12-oxophytodienoic acid

Roles as Enzyme Ligand

In Vivo Substrate in Enzyme-catalyzed Reactions (9 results)

EC NUMBER
PROVEN IN VIVO REACTION
REACTION DIAGRAM
LITERATURE
ENZYME 3D STRUCTURE
12-oxo-phytodienoic acid + glutathione = 10-S-glutathionyl-12-oxo-phytodienoic acid + H2O
show the reaction diagram
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In Vivo Product in Enzyme-catalyzed Reactions (3 results)

EC NUMBER
PROVEN IN VIVO REACTION
REACTION DIAGRAM
LITERATURE
ENZYME 3D STRUCTURE

Substrate in Enzyme-catalyzed Reactions (15 results)

EC NUMBER
REACTION
REACTION DIAGRAM
LITERATURE
ENZYME 3D STRUCTURE
ATP + 12-oxo-phytodienoic acid + CoA = AMP + diphosphate + 12-oxo-phytodienoyl-CoA
show the reaction diagram
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12-oxo-phytodienoic acid + CoA + ATP = 12-oxo-phytodienoyl-CoA + AMP + diphosphate
show the reaction diagram
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Product in Enzyme-catalyzed Reactions (8 results)

EC NUMBER
REACTION
REACTION DIAGRAM
LITERATURE
ENZYME 3D STRUCTURE
8-[(1R,2R)-3-oxo-2-((Z)-pent-2-enyl)cyclopentyl]octanoate + NADP+ = (15Z)-12-oxophyto-10,15-dienoate + NADPH + H+
show the reaction diagram
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13-hydroperoxylinolenic acid = 12-oxo-cis-10,15-phytodienoic acid + (12Z,15Z)-9-hydroxy-10-oxooctadeca-12,15-dienoic acid + H2O
show the reaction diagram
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Enzyme Kinetic Parameters

kcat Value (Turnover Number) (1 result)

EC NUMBER
TURNOVER NUMBER [1/S]
TURNOVER NUMBER MAXIMUM [1/S]
COMMENTARY
LITERATURE
1.56
-
pH not specified in the publication, temperature not specified in the publication

KM Value (6 results)

EC NUMBER
KM VALUE [MM]
KM VALUE MAXIMUM [MM]
COMMENTARY
LITERATURE

References & Links

Links to other databases for 12-oxo-phytodienoic acid

ChEBI
PubChem
ChEBI
PubChem