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Information on EC 2.7.7.66 - malonate decarboxylase holo-[acyl-carrier protein] synthase

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IUBMB Comments
The delta subunit of malonate decarboxylase serves as an an acyl-carrier protein (ACP) and contains the prosthetic group 2-(5-triphosphoribosyl)-3-dephospho-CoA. Two reactions are involved in the production of the holo-ACP form of this enzyme. The first reaction is catalysed by EC 2.4.2.52, triphosphoribosyl-dephospho-CoA synthase. The resulting prosthetic group is then attached to the ACP subunit via a phosphodiester linkage to a serine residue, thus forming the holo form of the enzyme, in a manner analogous to that of EC 2.7.7.61, citrate lyase holo-[acyl-carrier protein] synthase.
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The expected taxonomic range for this enzyme is: Klebsiella pneumoniae
Synonyms
2'-(5''-triphosphoribosyl)-3'-dephospho-CoA:apo ACP 2'-(5''-phosphoribosyl)-3'-dephospho-CoA transferase, MdcG, more
REACTION
REACTION DIAGRAM
COMMENTARY hide
ORGANISM
UNIPROT
LITERATURE
2'-(5-triphosphoribosyl)-3'-dephospho-CoA + malonate decarboxylase apo-[acyl-carrier protein] = malonate decarboxylase holo-[acyl-carrier protein] + diphosphate
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PATHWAY SOURCE
PATHWAYS
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