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Information on EC 2.1.1.258 - 5-methyltetrahydrofolate:corrinoid/iron-sulfur protein Co-methyltransferase

for references in articles please use BRENDA:EC2.1.1.258
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IUBMB Comments
Catalyses the transfer of a methyl group from the N5 group of methyltetrahydrofolate to the 5-methoxybenzimidazolylcobamide cofactor of a corrinoid/Fe-S protein. Involved, together with EC 1.2.7.4, carbon-monoxide dehydrogenase (ferredoxin) and EC 2.3.1.169, CO-methylating acetyl-CoA synthase, in the reductive acetyl coenzyme A (Wood-Ljungdahl) pathway of autotrophic carbon fixation in various bacteria and archaea.
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The enzyme appears in viruses and cellular organisms
Reaction Schemes
a [methyl-Co(III) corrinoid Fe-S protein]
+
=
a [Co(I) corrinoid Fe-S protein]
+
Synonyms
methyltetrahydrofolate- and corrinoid-dependent methyltransferase, more
REACTION
REACTION DIAGRAM
COMMENTARY hide
ORGANISM
UNIPROT
LITERATURE
a [methyl-Co(III) corrinoid Fe-S protein] + tetrahydrofolate = a [Co(I) corrinoid Fe-S protein] + 5-methyltetrahydrofolate
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