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Information on EC 2.1.1.197 - malonyl-[acyl-carrier protein] O-methyltransferase

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IUBMB Comments
Involved in an early step of biotin biosynthesis in Gram-negative bacteria. This enzyme catalyses the transfer of a methyl group to the omega-carboxyl group of malonyl-[acyl-carrier protein] forming a methyl ester. The methyl ester is recognized by the fatty acid synthetic enzymes, which process it via the fatty acid elongation cycle to give pimelyl-[acyl-carrier-protein] methyl ester . While the enzyme can also accept malonyl-CoA, it has a much higher activity with malonyl-[acyl-carrier protein]
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The enzyme appears in viruses and cellular organisms
Synonyms
sam-dependent methyltransferase, s-adenosyl-l-methionine-dependent methyltransferase, more
REACTION
REACTION DIAGRAM
COMMENTARY hide
ORGANISM
UNIPROT
LITERATURE
S-adenosyl-L-methionine + malonyl-[acyl-carrier protein] = S-adenosyl-L-homocysteine + malonyl-[acyl-carrier protein] methyl ester
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PATHWAY SOURCE
PATHWAYS
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