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Information on EC 1.14.14.95 - germacrene A hydroxylase

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IUBMB Comments
A heme-thiolate protein (P-450). This is probably part of the biosynthesis of many sesquiterpenoid lactones. In Lactuca sativa EC 1.14.13.123 is a mutifunctional enzyme with EC 1.1.1.314, germacrene A alcohol dehydrogenase .
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The enzyme appears in viruses and cellular organisms
Synonyms
germacrene a oxidase, (+)-germacrene a hydroxylase, more
REACTION
REACTION DIAGRAM
COMMENTARY hide
ORGANISM
UNIPROT
LITERATURE
(+)-germacrene A + 3 [reduced NADPH-hemoprotein reductase] + 3 O2 = germacra-1(10),4,11(13)-trien-12-oate + 3 [oxidized NADPH-hemoprotein reductase] + 4 H2O
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overall reaction
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(+)-germacrene A + O2 + [reduced NADPH-hemoprotein reductase] = germacra-1(10),4,11(13)-trien-12-ol + [oxidized NADPH-hemoprotein reductase] + H2O
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(1a)
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germacra-1(10),4,11(13)-trien-12-al + O2 + [reduced NADPH-hemoprotein reductase] = germacra-1(10),4,11(13)-trien-12-oate + [oxidized NADPH-hemoprotein reductase] + H2O
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(1c)
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germacra-1(10),4,11(13)-trien-12-ol + O2 + [reduced NADPH-hemoprotein reductase] = germacra-1(10),4,11(13)-trien-12-al + [oxidized NADPH-hemoprotein reductase] + 2 H2O
show the reaction diagram
(1b)
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