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Information on EC 1.14.14.37 - 4-hydroxyphenylacetaldehyde oxime monooxygenase

for references in articles please use BRENDA:EC1.14.14.37
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IUBMB Comments
This cytochrome P-450 (heme thiolate) enzyme is involved in the biosynthesis of the cyanogenic glucoside dhurrin in sorghum. It catalyses three different activities - isomerization of the (E) isomer to the (Z) isomer, dehydration, and C-hydroxylation.
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Word Map
The enzyme appears in viruses and cellular organisms
Synonyms
nadph-cytochrome p450 reductase, cyp71e1, cyp71e, more
REACTION
REACTION DIAGRAM
COMMENTARY hide
ORGANISM
UNIPROT
LITERATURE
(E)-4-hydroxyphenylacetaldehyde oxime + [reduced NADPH-hemoprotein reductase] + O2 = (S)-4-hydroxymandelonitrile + [oxidized NADPH-hemoprotein reductase] + 2 H2O
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overall reaction
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(E)-4-hydroxyphenylacetaldehyde oxime = (Z)-4-hydroxyphenylacetaldehyde oxime
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(1a)
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(Z)-4-hydroxyphenylacetaldehyde oxime = 4-hydroxyphenylacetonitrile + H2O
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(1b)
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4-hydroxyphenylacetonitrile + [reduced NADPH-hemoprotein reductase] + O2 = (S)-4-hydroxymandelonitrile + [oxidized NADPH-hemoprotein reductase] + H2O
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(1c)
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