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Information on EC 1.14.13.226 - acetone monooxygenase (methyl acetate-forming) for references in articles please use BRENDA:EC1.14.13.226Please wait a moment until all data is loaded. This message will disappear when all data is loaded.
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The expected taxonomic range for this enzyme is: Gordonia sp. TY-5
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acetone monooxygenase (methyl acetate-forming)
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acetone + NADPH + H+ + O2 = methyl acetate + NADP+ + H2O
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propane degradation I
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Propanoate metabolism
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acetone,NADPH:oxygen oxidoreductase (methyl acetate-forming)
Contains FAD. The enzyme, characterized from the bacterium Gordonia sp. TY-5, is a Baeyer-Villiger type monooxygenase and participates in a propane utilization pathway.
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UniProt
brenda
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acetone + NADPH + H+ + O2
methyl acetate + NADP+ + H2O
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enzyme catalyzes stoichiometric conversion of acetone to methyl acetate with consumption of NADPH
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?
butan-2-one + NADPH + H+ + O2
methyl propanoate + NADP+ + H2O
82% of the activity with acetone
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?
cyclobutanone + NADPH + H+ + O2
? + NADP+ + H2O
131% of the activity with acetone
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?
cyclohexanone + NADPH + H+ + O2
? + NADP+ + H2O
135% of the activity with acetone
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?
cyclopentanone + NADPH + H+ + O2
? + NADP+ + H2O
170% of the activity with acetone
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decan-2-one + NADPH + H+ + O2
methyl nonanoate + NADP+ + H2O
173% of the activity with acetone
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heptan-2-one + NADPH + H+ + O2
methyl hexanoate + NADP+ + H2O
80.7% of the activity with acetone
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?
nonan-2-one + NADPH + H+ + O2
methyl octanoate + NADP+ + H2O
186% of the activity with acetone
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?
octan-2-one + NADPH + H+ + O2
methyl heptanoate + NADP+ + H2O
128% of the activity with acetone
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?
pentan-2-one + NADPH + H+ + O2
methyl butanoate + NADP+ + H2O
45% of the activity with acetone
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?
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acetone + NADPH + H+ + O2
methyl acetate + NADP+ + H2O
A1IHE6
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enzyme catalyzes stoichiometric conversion of acetone to methyl acetate with consumption of NADPH
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?
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additional information
no cofactor: NADH
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63000
4 * 63000, SDS-PAGE
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tetramer
4 * 63000, SDS-PAGE
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A1IHE6_GORST
Gordonia sp. (strain TY-5)
533
59679
TrEMBL
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Kotani, T.; Yurimoto, H.; Kato, N.; Sakai, Y.
Novel acetone metabolism in a propane-utilizing bacterium, Gordonia sp. strain TY-5
J. Bacteriol.
189
886-893
2007
Gordonia sp. TY-5 (A1IHE6)
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