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(2E)-3-phenylprop-2-en-1-ol + O2
(2E)-3-phenylprop-2-enal + H2O2
-
-
-
?
(2E)-hept-2-en-1-ol + O2
(2E)-hept-2-enal + H2O2
31.9% of the activity with benzyl alcohol
-
-
?
(2E)-hex-2-en-1-ol + O2
(2E)-hex-2-enal + H2O2
(2E,4E)-hepta-2,4-dien-1-ol + O2
(2E,4E)-hepta-2,4-dienal + H2O2
737% of the activity with benzyl alcohol
-
-
?
(2E,4E)-hexa-2,4-dien-1-ol + O2
(2E,4E)-hexa-2,4-dienal + H2O2
807% of the activity with benzyl alcohol
-
-
?
(2E,4E)-hexa-2,4-dien-1-ol + O2
? + H2O2
282% of the activity with benzyl alcohol
-
-
?
(2H-1,3-benzodioxol-5-yl)methanol + O2
2H-1,3-benzodioxole-5-carbaldehyde + H2O2
301% of the activity with benzyl alcohol
-
-
?
(2R,3E)-4-(2,6,6-trimethylcyclohex-1-en-1-yl)but-3-en-2-ol + O2
(3E)-4-(2,6,6-trimethylcyclohex-1-en-1-yl)but-3-en-2-one + H2O2
4% conversion, 2% enantiomeric excess
-
-
?
(2R,3E)-4-(4-chlorophenyl)but-3-en-2-ol + O2
(3E)-4-(4-chlorophenyl)but-3-en-2-one + H2O2
10% conversion, 10% enantiomeric excess
-
-
?
(2R,3E)-4-(4-methylphenyl)but-3-en-2-ol + O2
(3E)-4-(4-methylphenyl)but-3-en-2-one + H2O2
13% conversion, 14% enantiomeric excess
-
-
?
(2R,3E)-4-phenylbut-3-en-2-ol + O2
(3E)-4-phenylbut-3-en-2-one + H2O2
29% conversion, 25% enantiomeric excess
-
-
?
(2R,3E)-oct-3-en-2-ol + O2
(3E)-oct-3-en-2-one + H2O2
16% conversion, 19% enantiomeric excess
-
-
?
(naphthalen-2-yl)methanol + O2
naphthalene-2-carbaldehyde + H2O2
874% of the activity with benzyl alcohol
-
-
?
(pyrene-1-yl)methanol + O2
pyrene-1-carbaldehyde + H2O2
35% of the activity with benzyl alcohol
-
-
?
(R,S)-4-methoxybenzyl alcohol + O2
1-(4-methoxyphenyl)ethanol + H2O2
(S)-1-(4-fluorophenyl)ethanol + O2
1-(4-fluorophenyl)acetaldehyde + H2O2
(S)-1-(4-methoxyphenyl)-ethanol + O2
1-(4-methoxyphenyl)acetaldehyde + H2O2
-
-
-
?
(thiophen-2-yl)methanol + O2
thiophene-2-carbaldehyde + H2O2
15.8% of the activity with benzyl alcohol
-
-
?
1,1'-binaphthalene + O2
?
1,2,3,4,5-pentachlorobenzene + O2
?
1,2,3,4-tetrachlorobenzene + O2
?
1,2,4,5-tetrachlorobenzene + O2
?
1-(2-naphthalenylmethyl)-naphthalene + O2
?
1-amino-9,10-anthracenedione + O2
?
1-chloro-9,10-anthracenedione + O2
?
1-naphthalene methanol + O2
alpha-naphthaldehyde + H2O2
-
27% of the activity with cinnamyl alcohol
-
-
?
2,4-dichloroaniline + O2
?
2,4-dimethoxybenzyl alcohol + O2
2,4-dimethoxybenzaldehyde + H2O2
2,4-dimethoxybenzyl alcohol + O2
2,4-dimethoxybenzyl aldehyde + H2O2
2,4-hexadien-1-ol + 2 O2
2,4-hexadienal + 2 H2O2
-
-
-
?
2,4-hexadien-1-ol + O2
2,4-hexadienal + H2O2
2,4-hexadien-1-ol + O2
2,4-hexandienal + H2O2
-
-
-
-
?
2,4-hexadien-1-ol + O2
?
-
-
-
?
2,4-hexadien-1-ol + O2
? + H2O2
2,4-hexadienal + O2
2,4-hexadienoate + H2O2
-
-
-
?
2,5-diformylfuran + 2 O2
2,5-furandicarboxylic acid + H2O2
-
-
-
ir
2,5-diformylfuran + O2
5-formylfuran-2-carboxylic acid + ?
2,5-diformylfuran + O2
formylfurancarboxylic acid + ?
2,6-dichloroaniline + O2
?
2-anisyl alcohol + O2
2-anisyl aldehyde + H2O2
96% of the activity with benzyl alcohol
-
-
?
2-hydroxybenzyl alcohol + O2
2-hydroxybenzaldehyde + H2O2
2-methoxybenzyl alcohol + O2
2-methoxybenzaldehyde + H2O
-
23% of the activity with 2-hydroxybenzyl alcohol
-
?
2-methoxybenzyl alcohol + O2
2-methoxybenzylaldehyde + H2O
2-methylbenzyl alcohol + O2
2-methylbenzylaldehyde + H2O
2-naphthalenemethanol + O2
2-naphthaleneformaldehyde + H2O
-
745.7% of the activity with benzyl alcohol
-
?
2-naphthalenemethanol + O2
?
-
-
-
-
?
2-naphthylmethanol + O2
2-naphthaldehyde + H2O2
2-phenylethyl alcohol + O2
2-phenylacetaldehyde + H2O
3,4-difluorobenzaldehyde + O2
3,4-difluorobenzoic acid + H2O2
-
-
-
?, r
3,4-dimethoxybenzyl alcohol + O2
3,4-dimethoxybenzaldehyde + H2O2
3,4-dimethoxybenzyl alcohol + O2
veratryl aldehyde + H2O2
3,5-dimethoxybenzyl alcohol + O2
3,5-dimethoxy benzaldehyde + H2O2
-
7% of the activity with 3,4-dimethoxybenzyl alcohol, VAO I. 8% of the activity with 3,4-dimethoxybenzyl alcohol, VAO II
-
-
?
3-anisyl alcohol + O2
3-anisaldehyde + H2O2
-
-
-
?
3-anisyl alcohol + O2
3-anisyl aldehyde + H2O2
3-chloro-4-anisaldehyde + O2
3-chloro-4-anisic acid + H2O2
-
-
-
r
3-chloro-4-anisyl alcohol + O2
3-chloro-4-anisaldehyde + H2O2
-
-
-
?
3-chloro-4-anisyl alcohol + O2
3-chloro-4-anisyl aldehyde + H2O2
-
high activity
-
-
?
3-chloro-4-methoxybenzyl alcohol + O2
3-chloro-4-methoxybenzaldehyde + H2O2
ternary mechanism
-
-
?
3-chlorobenzaldehyde + O2
3-chlorobenzoic acid + H2O2
-
-
-
r
3-chlorobenzyl alcohol + O2
3-chlorobenzaldehyde + H2O2
3-chlorobenzyl alcohol + O2
3-chlorobenzyl aldehyde + H2O2
-
-
-
-
?
3-fluorobenzaldehyde + O2
3-fluorobenzoic acid + H2O2
-
-
-
r
3-fluorobenzyl alcohol + O2
3-fluorobenzaldehyde + H2O2
3-fluorobenzyl alcohol + O2
3-fluorobenzyl aldehyde + H2O2
-
low activity
-
-
?
3-fluorobenzyl alcohol + O2
?
-
-
-
?
3-hydroxy-4-methoxybenzyl alcohol + O2
3-hydroxy-4-methoxybenzaldehyde + H2O2
-
62% of the activity with 3,4-dimethoxybenzyl alcohol, VAO I. 71% of the activity with 3,4-dimethoxybenzyl alcohol, VAO II
-
-
?
3-hydroxybenzyl alcohol + O2
3-hydroxybenzaldehyde + H2O2
3-hydroxybenzyl alcohol + O2
3-hydroxybenzyl aldehyde + H2O2
221% of the activity with benzyl alcohol
-
-
?
3-methoxybenzyl alcohol + O2
3-methoxybenzaldehyde + H2O2
3-methoxybenzyl alcohol + O2
3-methoxybenzylaldehyde + H2O2
recombinant enzyme shows 1% of the activity with 2-hydroxybenzyl alcohol
-
-
?
3-phenoxybenzyl alcohol + O2
3-phenoxybenzaldehyde + H2O2
-
35% of the activity with 3,4-dimethoxybenzyl alcohol, VAO I. 18% of the activity with 3,4-dimethoxybenzyl alcohol, VAO II
-
-
?
4-aminobenzyl alcohol + O2
4-aminobenzaldehyde + H2O2
18.6% of the activity with benzyl alcohol
-
-
?
4-anisaldehyde + O2
4-anisic acid + H2O2
4-anisyl alcohol + O2
4-anisaldehyde + H2O2
4-anisyl alcohol + O2
4-anisyl aldehyde + H2O2
4-chlorobenzaldehyde + O2
4-chlorobenzoic acid + H2O2
-
-
-
r
4-chlorobenzyl alcohol + O2
4-chlorobenzaldehyde + H2O2
4-chlorobenzyl alcohol + O2
4-chlorobenzyl aldehyde + H2O2
-
-
-
-
?
4-fluorobenzaldehyde + O2
4-fluorobenzoic acid + H2O2
-
-
-
r
4-fluorobenzyl alcohol + O2
4-fluorobenzaldehyde + H2O2
-
-
-
?
4-fluorobenzyl alcohol + O2
4-fluorobenzyl aldehyde + H2O2
-
-
-
-
?
4-hydroxy-3-methoxybenzyl alcohol + O2
4-hydroxy-3-methoxybenzaldehyde + H2O2
4-hydroxybenzyl alcohol + O2
4-hydroxybenzaldehyde + H2O2
4-hydroxybenzyl alcohol + O2
4-hydroxybenzyl aldehyde + H2O2
4-methoxybenzyl alcohol + O2
4-methoxybenzaldehyde + H2O2
4-methoxybenzyl alcohol + O2
4-methoxybenzyl aldehyde + H2O2
4-methoxycinnamyl alcohol + O2
4-methoxycinnamaldehyde + H2O2
-
-
-
r
4-nitrobenzaldehyde + O2
4-nitrobenzoic acid + H2O2
-
-
-
?, r
4-nitrobenzyl alcohol + O2
4-nitrobenzaldehyde + H2O2
-
-
-
r
5-(hydroxymethyl)furan-2-carboxylic acid + O2
2,5-formylfurancarboxylic acid + H2O2
-
-
-
?
5-(hydroxymethyl)furan-2-carboxylic acid + O2
2,5-furandicarboxylic acid + ?
very low activity
-
-
?
5-(hydroxymethyl)furan-2-carboxylic acid + O2
furan-2,5-dicarboxylic acid + ?
5-(hydroxymethyl)furfural + O2
furan-2,5-dicarbaldehyde + H2O2
5-formylfuran-2-carboxylate + O2
furan-2,5-dicarboxylate + H2O2
5-hydroxymethylfurfural + O2
2,5-diformylfuran + 5-formylfuran-2-carboxylic acid + H2O2
5-hydroxymethylfurfural + O2
2,5-diformylfuran + H2O2
5-hydroxymethylfurfural + O2
2,5-furandicarboxylic acid + ?
5-hydroxymethylfurfural + O2
5-(hydroxymethyl)furan-2-carboxylic acid + H2O2
7H-benz[DE]anthracen-7-one + O2
?
9,10-anthracenedione + O2
?
anisyl alcohol + O2
anisaldehyde + H2O2
anisyl alcohol + O2
anisyl aldehyde + H2O2
benzaldehyde + O2
benzoic acid + H2O2
-
-
-
r
benzyl alcohol + O2
benzaldehyde + H2O2
benzyl alcohol + O2
benzyl aldehyde + H2O2
beta-naphthylcarbinol + O2
beta-naphthaldehyde + H2O2
cinnamyl alcohol + O2
cinnamaldehyde + H2O2
cinnamyl alcohol + O2
cinnamic aldehyde + H2O2
cinnamyl alcohol + O2
cinnamyl aldehyde + H2O2
coniferyl alcohol + O2
coniferyl aldehyde + H2O2
-
13% of the activity with cinnamyl alcohol
-
-
?
cumic alcohol + O2
cumic aldehyde + H2O2
149% of the activity with benzyl alcohol
-
-
?
cyclohexyl alcohol + O2
cyclohexyl aldehyde + H2O2
-
12% of the activity with cinnamyl alcohol
-
-
?
Direct Red 5B + O2
3-diazenyl-7-[(phenylcarbonyl)amino]naphthalene-2-sulfonic acid + H2O2
-
degradation, dye decolorizing
product identification by GC-MS analysis
-
?
ethanol + O2
acetaldehyde + H2O2
formylfurancarboxylic acid + O2
2,5-furandicarboxylic acid + H2O2
furan-2,5-dicarbaldehyde + O2
5-formylfuran-2-carboxylate + H2O2
isovanillyl alcohol + O2
isovanillyl aldehyde + H2O2
m-anisyl alcohol + O2
m-anisaldehyde + H2O2
N-phenyl-1-naphthalenamine + O2
?
n-propanol + O2
propionaldehyde + H2O2
vanillyl alcohol + O2
vanillyl aldehyde + H2O2
-
-
-
?
veratraldehyde + O2
veratric acid + H2O2
-
-
-
r
veratryl alcohol + 2,6-dichlorophenol indophenol
veratrylaldehyde + red. 2,6-dichlorophenol indophenol
-
-
-
-
?
veratryl alcohol + O2
? + H2O2
-
-
-
-
?
veratryl alcohol + O2
veratraldehyde + H2O2
veratryl alcohol + O2
veratryl aldehyde + H2O2
veratryl alcohol + O2
veratrylaldehyde + H2O2
additional information
?
-
(2E)-hex-2-en-1-ol + O2
(2E)-hex-2-enal + H2O2
-
-
-
?
(2E)-hex-2-en-1-ol + O2
(2E)-hex-2-enal + H2O2
63.9% of the activity with benzyl alcohol
-
-
?
(R,S)-4-methoxybenzyl alcohol + O2
1-(4-methoxyphenyl)ethanol + H2O2
-
-
-
-
?
(R,S)-4-methoxybenzyl alcohol + O2
1-(4-methoxyphenyl)ethanol + H2O2
over 98% excess of the R enantiomer after treatment of racemic 1-(4-methoxyphenyl)ethanol, the hydride transfer is highly stereoselective
-
-
?
(S)-1-(4-fluorophenyl)ethanol + O2
1-(4-fluorophenyl)acetaldehyde + H2O2
-
-
-
?
(S)-1-(4-fluorophenyl)ethanol + O2
1-(4-fluorophenyl)acetaldehyde + H2O2
mutant F501A
-
-
?
1,1'-binaphthalene + O2
?
-
low activity
-
-
?
1,1'-binaphthalene + O2
?
-
degradation, partial removal from soil
-
-
?
1,2,3,4,5-pentachlorobenzene + O2
?
-
very low activity
-
-
?
1,2,3,4,5-pentachlorobenzene + O2
?
-
degradation, partial removal from soil
-
-
?
1,2,3,4-tetrachlorobenzene + O2
?
-
high activity
-
-
?
1,2,3,4-tetrachlorobenzene + O2
?
-
degradation, complete removal from soil
-
-
?
1,2,4,5-tetrachlorobenzene + O2
?
-
high activity
-
-
?
1,2,4,5-tetrachlorobenzene + O2
?
-
degradation, complete removal from soil
-
-
?
1,2-binaphthalene + O2
?
-
low activity
-
-
?
1,2-binaphthalene + O2
?
-
degradation, partial removal from soil
-
-
?
1-(2-naphthalenylmethyl)-naphthalene + O2
?
-
-
-
-
?
1-(2-naphthalenylmethyl)-naphthalene + O2
?
-
degradation, partial removal from soil
-
-
?
1-amino-9,10-anthracenedione + O2
?
-
lower activity
-
-
?
1-amino-9,10-anthracenedione + O2
?
-
degradation, partial removal from soil
-
-
?
1-chloro-9,10-anthracenedione + O2
?
-
very low activity
-
-
?
1-chloro-9,10-anthracenedione + O2
?
-
degradation, partial removal from soil
-
-
?
2,4-dichloroaniline + O2
?
-
high activity
-
-
?
2,4-dichloroaniline + O2
?
-
degradation, complete removal from soil
-
-
?
2,4-dimethoxybenzyl alcohol + O2
2,4-dimethoxybenzaldehyde + H2O2
-
-
-
r
2,4-dimethoxybenzyl alcohol + O2
2,4-dimethoxybenzaldehyde + H2O2
-
177.5% of the activity with benzyl alcohol
-
?
2,4-dimethoxybenzyl alcohol + O2
2,4-dimethoxybenzaldehyde + H2O2
-
-
-
-
?
2,4-dimethoxybenzyl alcohol + O2
2,4-dimethoxybenzyl aldehyde + H2O2
286% of the activity with benzyl alcohol
-
-
?
2,4-dimethoxybenzyl alcohol + O2
2,4-dimethoxybenzyl aldehyde + H2O2
-
50% of the activity with 3,4-dimethoxybenzyl alcohol, VAO I. 75% of the activity with 3,4-dimethoxybenzyl alcohol, VAO II
-
-
?
2,4-hexadien-1-ol + O2
2,4-hexadienal + H2O2
-
-
-
-
?
2,4-hexadien-1-ol + O2
2,4-hexadienal + H2O2
-
-
-
?
2,4-hexadien-1-ol + O2
2,4-hexadienal + H2O2
-
high activity
-
-
?
2,4-hexadien-1-ol + O2
? + H2O2
-
531% of the activity with benzyl alcohol
-
?
2,4-hexadien-1-ol + O2
? + H2O2
-
-
-
-
?
2,5-diformylfuran + O2
5-formylfuran-2-carboxylic acid + ?
-
-
-
?
2,5-diformylfuran + O2
5-formylfuran-2-carboxylic acid + ?
-
-
-
?
2,5-diformylfuran + O2
formylfurancarboxylic acid + ?
-
-
-
?
2,5-diformylfuran + O2
formylfurancarboxylic acid + ?
-
-
-
-
?
2,6-dichloroaniline + O2
?
-
high activity
-
-
?
2,6-dichloroaniline + O2
?
-
degradation, complete removal from soil
-
-
?
2-hydroxybenzyl alcohol + O2
2-hydroxybenzaldehyde + H2O2
-
-
-
?
2-hydroxybenzyl alcohol + O2
2-hydroxybenzaldehyde + H2O2
-
i.e. salicyl alcohol
-
?
2-hydroxybenzyl alcohol + O2
2-hydroxybenzaldehyde + H2O2
i.e. salicyl alcohol
-
-
?
2-hydroxybenzyl alcohol + O2
2-hydroxybenzaldehyde + H2O2
essential for the activation of the plant derived precursor salicin
-
-
?
2-hydroxybenzyl alcohol + O2
2-hydroxybenzaldehyde + H2O2
-
-
-
?
2-hydroxybenzyl alcohol + O2
2-hydroxybenzaldehyde + H2O2
i.e. salicyl alcohol
-
-
?
2-hydroxybenzyl alcohol + O2
2-hydroxybenzaldehyde + H2O2
essential for the activation of the plant derived precursor salicin
-
-
?
2-hydroxybenzyl alcohol + O2
2-hydroxybenzaldehyde + H2O2
-
i.e. salicyl alcohol
-
?
2-methoxybenzyl alcohol + O2
2-methoxybenzylaldehyde + H2O
-
14% of the activity with 2-hydroxybenzyl alcohol
-
?
2-methoxybenzyl alcohol + O2
2-methoxybenzylaldehyde + H2O
recombinant enzyme shows 3.2% of the activity with 2-hydroxybenzyl alcohol, native enzyme shows 14% of the activity with 2-hydroxybenzyl alcohol
-
-
?
2-methoxybenzyl alcohol + O2
2-methoxybenzylaldehyde + H2O
recombinant enzyme shows 2.3% of the activity with 2-hydroxybenzyl alcohol
-
-
?
2-methylbenzyl alcohol + O2
2-methylbenzylaldehyde + H2O
-
21% of the activity with 2-hydroxybenzyl alcohol
-
?
2-methylbenzyl alcohol + O2
2-methylbenzylaldehyde + H2O
recombinant enzyme shows 19.1% of the activity with 2-hydroxybenzyl alcohol, native enzyme shows 21% of the activity with 2-hydroxybenzyl alcohol
-
-
?
2-methylbenzyl alcohol + O2
2-methylbenzylaldehyde + H2O
recombinant enzyme shows 21.9% of the activity with 2-hydroxybenzyl alcohol
-
-
?
2-naphthylmethanol + O2
2-naphthaldehyde + H2O2
-
-
-
r
2-naphthylmethanol + O2
2-naphthaldehyde + H2O2
best substrate
-
-
r
2-phenylethyl alcohol + O2
2-phenylacetaldehyde + H2O
-
21% of the activity with 2-hydroxybenzyl alcohol
-
?
2-phenylethyl alcohol + O2
2-phenylacetaldehyde + H2O
recombinant enzyme shows 3.8% of the activity with 2-hydroxybenzyl alcohol, native enzyme shows 21% of the activity with 2-hydroxybenzyl alcohol
1.1.3.7 aryl-alcohol oxidase
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