EC Explorer

5.5.1.14

syn-copalyl-diphosphate synthase

geranylgeranyl diphosphate = 9α-copalyl diphosphate

OsCyc1, OsCPSsyn, syn-CPP synthase, syn-copalyl diphosphate synthase, 9α-copalyl-diphosphate lyase (decyclizing)

9α-copalyl-diphosphate lyase (ring-opening)

Requires a divalent metal ion, preferably Mg²⁺, for activity. This class II terpene synthase produces syn-copalyl diphosphate, a precursor of several rice phytoalexins, including oryzalexin S and momilactones A and B. Phytoalexins are diterpenoid secondary metabolites that are involved in the defense mechanism of the plant, and are produced in response to pathogen attack through the perception of elicitor signal molecules such as chitin oligosaccharide, or after exposure to UV irradiation. The enzyme is constitutively expressed in the roots of plants where one of its products, momilactone B, acts as an allelochemical (a molecule released into the environment to suppress the growth of neighbouring plants). In other tissues the enzyme is upregulated by conditions that stimulate the biosynthesis of phytoalexins.

created 2008