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EC 1.2.1.58 Details
EC number
1.2.1.58
Accepted name
phenylglyoxylate dehydrogenase (acylating)
Reaction
phenylglyoxylate + NAD+ + CoA = benzoyl-S-CoA + CO2 + NADH
Systematic name
phenylglyoxylate:NAD+ oxidoreductase
CAS registry number
205510-78-7
Comment
Requires thiamine diphosphate as cofactor. The enzyme from the denitrifying bacterium Azoarcus evansii is specific for phenylglyoxylate. 2-Oxoisovalerate is oxidized at 15% of the rate for phenylglyoxylate. Also reduces viologen dyes. Contains iron-sulfur centres and FAD.
History
created 1999
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