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EC 5.3.2.8 Details
EC number
5.3.2.8
Accepted name
4-oxalomesaconate tautomerase
Reaction
(1E)-4-oxobut-1-ene-1,2,4-tricarboxylate = (1E,3E)-4-hydroxybuta-1,3-diene-1,2,4-tricarboxylate
Other name(s)
GalD
Systematic name
4-oxalomesaconate ketoenol-isomerase
Comment
This enzyme has been characterized from the bacterium Pseudomonas putida KT2440 and is involved in the degradation pathway of syringate and 3,4,5-trihydroxybenzoate. It catalyses the interconversion of two of the tautomers of 4-oxalomesaconate, a reaction that can also occur spontaneously.
History
created 2011 as EC 5.3.3.16, modified 2011, transferred 2012 to EC 5.3.2.8
EC Tree
1.14.13.45 created 1992, deleted 2003
1.14.17.2 created 1972, deleted 1984