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butyl acetate
synthesis of (R)-beta-nitro alcohols, highest enantioselectivity is obtained with n-butyl acetate as solvent with an optimum aqueous phase content of 50% (v/v)
additional information
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effect of different organic solvents on the hydrocyanation of acetophenone tested
dibutyl ether
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more than 80% residual activity after incubation for 12 h in the system of methyl-tert-butyl ether, dibutyl ether, hexane, and diisopropyl ether while diethyl ether and ethyl acetate are not suitable solvents
dibutyl ether
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EjHNL is very stable in ethyl acetate, diethyl ether, methyl-tert-butyl ether, diisopropyl ether, dibutyl ether and hexane for 12 h. The best solvent for the highest initial velocity and enantiomeric excess is diethyl ether with an optimum aqueous phase content of 50% (v/v)
diethyl ether
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more than 80% residual activity after incubation for 12 h in the system of methyl-tert-butyl ether, dibutyl ether, hexane, and diisopropyl ether while diethyl ether and ethyl acetate are not suitable solvents
diethyl ether
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EjHNL is very stable in ethyl acetate, diethyl ether, methyl-tert-butyl ether, diisopropyl ether, dibutyl ether and hexane for 12 h. The best solvent for the highest initial velocity and enantiomeric excess is diethyl ether with an optimum aqueous phase content of 50% (v/v)
diisopropyl ether
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more than 80% residual activity after incubation for 12 h in the system of methyl-tert-butyl ether, dibutyl ether, hexane, and diisopropyl ether while diethyl ether and ethyl acetate are not suitable solvents
diisopropyl ether
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EjHNL is very stable in ethyl acetate, diethyl ether, methyl-tert-butyl ether, diisopropyl ether, dibutyl ether and hexane for 12 h. The best solvent for the highest initial velocity and enantiomeric excess is diethyl ether with an optimum aqueous phase content of 50% (v/v)
Ethyl acetate
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more than 80% residual activity after incubation for 12 h in the system of methyl-tert-butyl ether, dibutyl ether, hexane, and diisopropyl ether while diethyl ether and ethyl acetate are not suitable solvents
Ethyl acetate
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EjHNL is very stable in ethyl acetate, diethyl ether, methyl-tert-butyl ether, diisopropyl ether, dibutyl ether and hexane for 12 h. The best solvent for the highest initial velocity and enantiomeric excess is diethyl ether with an optimum aqueous phase content of 50% (v/v)
hexane
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more than 80% residual activity after incubation for 12 h in the system of methyl-tert-butyl ether, dibutyl ether, hexane, and diisopropyl ether while diethyl ether and ethyl acetate are not suitable solvents
hexane
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EjHNL is very stable in ethyl acetate, diethyl ether, methyl-tert-butyl ether, diisopropyl ether, dibutyl ether and hexane for 12 h. The best solvent for the highest initial velocity and enantiomeric excess is diethyl ether with an optimum aqueous phase content of 50% (v/v)
methyl-tert-butylether
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more than 80% residual activity after incubation for 12 h in the system of methyl-tert-butyl ether, dibutyl ether, hexane, and diisopropyl ether while diethyl ether and ethyl acetate are not suitable solvents
methyl-tert-butylether
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EjHNL is very stable in ethyl acetate, diethyl ether, methyl-tert-butyl ether, diisopropyl ether, dibutyl ether and hexane for 12 h. The best solvent for the highest initial velocity and enantiomeric excess is diethyl ether with an optimum aqueous phase content of 50% (v/v)