4.1.1.7: benzoylformate decarboxylase

This is an abbreviated version!
For detailed information about benzoylformate decarboxylase, go to the full flat file.

Word Map on EC 4.1.1.7

Reaction

phenylglyoxylate
=
benzaldehyde
+
CO2

Synonyms

Phenylglyoxylate decarboxylase, Decarboxylase, benzoylformate, BFD, BFDC, MdlC, BfdB, BfdM, benzoylformate decarboxylase

ECTree

     4 Lyases
         4.1 Carbon-carbon lyases
             4.1.1 Carboxy-lyases
                4.1.1.7 benzoylformate decarboxylase

KM Value

KM Value on EC 4.1.1.7 - benzoylformate decarboxylase

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KM VALUE [mM]
SUBSTRATE
ORGANISM
UNIPROT
COMMENTARY hide
LITERATURE
IMAGE
0.056
(p-methoxybenzoyl)formate
-
-
0.19 - 0.58
(p-methylbenzoyl)formate
62
(R)-2-hydroxy-1-phenylpropanone
-
at pH 7.5 and 30°C
62
(S)-2-hydroxy-1-phenylpropanone
-
at pH 7.5 and 30°C
0.42 - 7.5
2-ketobutanoate
0.15 - 4.1
2-ketohexanoate
0.1 - 6
2-ketopentanoate
1.1
2-oxo-4-methylhexanoic acid
pH 6.0, 30°C, mutant enzyme A460I
3.4 - 9.6
2-oxo-4-methylpentanoic acid
0.39 - 4.1
2-oxobutanoate
18.3
2-oxobutanoic acid
pH 6.0, 30°C, mutant enzyme A460I
0.14 - 21
2-Oxohexanoate
1 - 4.1
2-oxohexanoic acid
0.15 - 11
2-oxopentanoate
1.2 - 6
2-Oxopentanoic acid
0.77
3-methyl-2-oxobutanoate
mutant enzyme T377L/A460Y, at pH 6.0 and 30°C
1.2
3-methyl-2-oxopentanoate
mutant enzyme T377L/A460Y, at pH 6.0 and 30°C
0.14 - 9.6
4-methyl-2-oxopentanoate
0.14 - 21
4-methylthio-2-oxobutanoate
310 - 775
acetaldehyde
19.4 - 77
benzaldehyde
0.059 - 15
benzoylformate
0.04 - 1.5
benzylformate
0.76
methyl benzoylphosphonate
-
0.15
p-nitro-benzoylformate
at 25°C
0.27 - 7.8
phenylglyoxylate
0.82
phenylpyruvate
mutant enzyme T377L/A460Y, at pH 6.0 and 30°C
2 - 21
pyruvate
0.023
[m-(fluoromethyl)benzoyl]formate
-
-
0.021 - 0.18
[p-(Chloromethyl)benzoyl]formate
0.19
[p-(Fluoromethyl)benzoyl]formate
-
-
additional information
additional information
-