3.5.1.67: 4-methyleneglutaminase
This is an abbreviated version!
For detailed information about 4-methyleneglutaminase, go to the full flat file.
Word Map on EC 3.5.1.67
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3.5.1.67
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acetamide
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smegmatis
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nidulans
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creatinase
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tetrahedral
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binuclear
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cis-dominant
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sarcosine
- 3.5.1.67
- acetamide
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smegmatis
-
nidulans
- creatinase
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tetrahedral
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binuclear
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cis-dominant
- sarcosine
Reaction
Synonyms
4-methyleneglutamine amidohydrolase, 4-methyleneglutamine deamidase, amidase, 4-methyleneglutamine, MeGln amidohydrolase
ECTree
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Substrates Products
Substrates Products on EC 3.5.1.67 - 4-methyleneglutaminase
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REACTION DIAGRAM
4-methyl-L-glutamine + H2O
4-methyl-L-glutamate + NH3
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about 9% of the rate of 4-methylene-L-glutamine hydrolysis
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?
L-glutamate-5-ethyl ester + H2O
?
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about 1.6% of the rate of 4-methylene-L-glutamine hydrolysis
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?
L-glutamate-5-hydroxamate + H2O
?
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about 6.6% of the rate of 4-methylene-L-glutamine hydrolysis
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?
L-glutamate-5-methyl ester + H2O
?
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about 9% of the rate of 4-methylene-L-glutamine hydrolysis
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-
?
4-methylene-L-glutamine + H2O
4-methylene-L-glutamate + NH3
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highly specific
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?
4-methylene-L-glutamine + H2O
4-methylene-L-glutamate + NH3
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highly specific
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?
4-methylene-L-glutamine + H2O
?
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implicated in the process of N-translocation
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-
?
4-methylene-L-glutamine + H2O
?
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key evidence in establishing N-translocating role for this nonprotein amino acid
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?
4-methylene-L-glutamine + H2O
?
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initial enzyme for catalyzing 4-methylene-L-glutamine degradation
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?
4-methylene-L-glutamine + H2O
?
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implicated in the transport of nitrogen to the developing shoots and leaves of germinating peanuts, involved in releasing nitrogen to the plants
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-
?
L-glutamine + H2O
L-glutamate + NH3
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about 20% of the rate of 4-methylene-L-glutamine hydrolysis
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?
L-glutamine + H2O
L-glutamate + NH3
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about 20% of the rate of 4-methylene-L-glutamine hydrolysis
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-
?
additional information
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hydrolyses compounds with substituents on the amide group, e.g. esters and the hydroxamic acid derivative
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additional information
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L-N5-ethylglutamine, theanine, N-methyl-DL-glutamic acid, N-carbobenzoxy-L-glutamic acid, L-glutamic acid diethyl ester, N-acetyl-L-glutamine, D-glutamine, L-asparagine, O-carbamoyl-L-serine, S-carbamoyl-L-cysteine, albizziine, N-acetyl-L-glutamic acid: no substrates
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?
additional information
?
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5-carbon amino acid amide structure is essential for activity
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?
additional information
?
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glutaramic acid, glutarimide, acrylamide, methacrylamide, succinamic acid, acetamide, urea, N-benzoyl-4-methylene-L-glutamine, isoglutamine, 4-methyleneisoglutamine: no substrates
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?
additional information
?
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implicated in the process of N-translocation
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?
additional information
?
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implicated in the process of N-translocation
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?