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3.2.1.40: alpha-L-rhamnosidase

This is an abbreviated version!
For detailed information about alpha-L-rhamnosidase, go to the full flat file.

Word Map on EC 3.2.1.40

Reaction

4',5,7-trihydroxyflavanone 7-rhamnoglucoside
+
H2O
=
4',5,7-trihydroxyflavanone 7-glucoside
+
alpha-L-rhamnose

Synonyms

alpha-L-rhamnosidase, alpha-L-rhamnosidase A, alpha-L-rhamnosidase B, alpha-L-rhamnosidase N, alpha-L-rhamnosidase Ram A, alpha-L-rhamnosidase T, alpha-RHA, AoRha, AorhaA, BtRha, BtRha78A, DtRha, EC 3.2.1.66, GH106 alpha-L-rhamnosidase, gypenoside-alpha-L-rhamnosidase, KoRha, L-rhamnosidase, More, naringinase, pnp-rhamnohydrolase, RamA, RHA-P, RhaA, RhaB, RhaB1, RhaB2, RhaL1, Rham, rhamnosidase, alpha -L-, RhmA, saponin-alpha-L-rhamnosidase

ECTree

     3 Hydrolases
         3.2 Glycosylases
             3.2.1 Glycosidases, i.e. enzymes that hydrolyse O- and S-glycosyl compounds
                3.2.1.40 alpha-L-rhamnosidase

Substrates Products

Substrates Products on EC 3.2.1.40 - alpha-L-rhamnosidase

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SUBSTRATE
PRODUCT                       
REACTION DIAGRAM
ORGANISM
UNIPROT
COMMENTARY
(Substrate) hide
LITERATURE
(Substrate)
COMMENTARY
(Product) hide
LITERATURE
(Product)
Reversibility
r=reversible
ir=irreversible
?=not specified
2-phenylethyl beta-D-rutinoside + H2O
2-phenylethyl beta-D-glucopyranoside + alpha-L-rhamnose
show the reaction diagram
-
-
-
-
?
20(S)-ginsenoside Rg2 + H2O
20(S)-ginsenoside Rh1 + alpha-L-rhamnose
show the reaction diagram
-
low activity cleaving the alpha-1,2-linkage
-
-
?
3-O-alpha-L-rhamnopyranosyl-alpha-D-mannopyranoside + H2O
alpha-L-rhamnose + alpha-D-mannose
show the reaction diagram
-
-
-
-
?
4',5,7-trihydroxyflavanone 7-rhamnoglucoside + H2O
4',5,7-trihydroxyflavanone 7-glucoside + alpha-L-rhamnose
show the reaction diagram
4-nitrophenyl alpha-L-rhamnopyranoside + H2O
4-nitrophenol + alpha-L-rhamnopyranose
show the reaction diagram
4-nitrophenyl alpha-L-rhamnopyranoside + H2O
4-nitrophenol + alpha-L-rhamnose
show the reaction diagram
4-nitrophenyl alpha-L-rhamnoside + H2O
alpha-L-rhamnose + 4-nitrophenol
show the reaction diagram
4-nitrophenyl beta-D-glucopyranoside + H2O
4-nitrophenol + D-glucopyranose
show the reaction diagram
-
-
2.1% of activity compared to p-nitrophenyl-alpha-L-rhamnopyranoside
-
?
4-nitrophenyl-alpha-L-rhamnopyranoside + H2O
4-nitrophenol + alpha-L-rhamnopyranose
show the reaction diagram
4-nitrophenyl-alpha-L-rhamnopyranoside + H2O
alpha-L-rhamnose + 4-nitrophenol
show the reaction diagram
-
-
-
?
6-O-alpha-L-rhamnosyl-D-glucopyranose + H2O
alpha-L-rhamnose + D-glucose
show the reaction diagram
-
rutinose
-
-
?
alpha-L-rhamnoside + H2O
alpha-L-rhamnose + ?
show the reaction diagram
convallotoxin + H2O
strophantidin + alpha-L-rhamnose
show the reaction diagram
-
-
-
-
?
dulcoside A + H2O
rubusoside + alpha-L-rhamnose
show the reaction diagram
no hydrolytic activity against dulcoside A analogues. No transrhamnosylation activity is observed
-
-
?
epimedin C + H2O
icariin + alpha-L-rhamnopyranose
show the reaction diagram
frangulin + H2O
frangula emodin + alpha-L-rhamnose
show the reaction diagram
-
-
-
-
?
gellan + H2O
alpha-L-rhamnose + ?
show the reaction diagram
gellan + H2O
L-rhamnose + ?
show the reaction diagram
geranyl-beta-D-rutinoside + H2O
geranyl-beta-D-glycoside + alpha-L-rhamnose
show the reaction diagram
-
-
-
-
?
ginsenoside Rg2 + H2O
ginsenoside Rh1 + alpha-L-rhamnose
show the reaction diagram
gypenoside-5 + H2O
ginsenoside Rd + alpha-L-rhamnose
show the reaction diagram
hesperidin + H2O
?
show the reaction diagram
-
34% of activity compared to naringin
-
-
?
hesperidin + H2O
? + alpha-L-rhamnose
show the reaction diagram
cleavage of the alpha-1,6-linkage
-
-
?
hesperidin + H2O
hesperetin 7-glucoside + alpha-L-rhamnose
show the reaction diagram
hesperidin + H2O
hesperetin 7-O-beta-D-glucoside + alpha-L-rhamnose
show the reaction diagram
hesperidin + H2O
hesperetin 7-O-beta-D-glucoside + L-rhamnose
show the reaction diagram
-
-
-
-
?
hesperidin + H2O
hesperetin 7-O-glucoside + alpha-L-rhamnose
show the reaction diagram
hesperidin + H2O
L-rhamnose + ?
show the reaction diagram
-
-
-
?
high-methoxyl pectin + H2O
pyranoside + alpha-L-rhamnose
show the reaction diagram
-
-
-
-
?
methyl 3-O-alpha-L-rhamnopyranosyl-alpha-D-mannopyranoside + H2O
alpha-L-rhamnose + methyl alpha-D-mannose
show the reaction diagram
-
-
-
-
?
methyl 3-O-alpha-L-rhamnopyranosyl-alpha-D-xylopyranoside + H2O
alpha-L-rhamnose + methyl alpha-D-xylose
show the reaction diagram
-
-
-
-
?
methyl 3-O-alpha-L-rhamnopyranosyl-alpha-L-rhamnopyranoside + H2O
alpha-L-rhamnose + methyl alpha-L-rhamnose
show the reaction diagram
-
-
-
-
?
methyl 4-O-alpha-L-rhamnopyranosyl-alpha-D-galactopyranoside + H2O
alpha-L-rhamnose + methyl alpha-D-galactose
show the reaction diagram
-
-
-
-
?
methyl 4-O-alpha-L-rhamnopyranosyl-alpha-D-mannopyranoside + H2O
alpha-L-rhamnose + methyl alpha-D-mannose
show the reaction diagram
-
-
-
-
?
methyl 4-O-alpha-L-rhamnopyranosyl-alpha-D-xylopyranoside + H2O
alpha-L-rhamnose + alpha-D-xylose
show the reaction diagram
-
-
-
-
?
muscat glycoside extract
linalool + alpha-terpineol + citronellol + nerol + geraniol + ?
show the reaction diagram
-
-
-
-
?
myricetrin + H2O
3,5,7-trihydroxy-2-(3,4,5-trihydroxyphenyl)-4H-chromen-4-one + alpha-L-rhamnose
show the reaction diagram
22.5% of the activity compared to naringin
-
-
?
myricitrin + H2O
3,5,7-trihydroxy-2-(3,4,5-trihydroxyphenyl)-4H-chromen-4-one + alpha-L-rhamnose
show the reaction diagram
low activity
-
-
?
myricitrin + H2O
L-rhamnose + myricetin
show the reaction diagram
-
myricitrin is identical with myricetin-3-L-rhamnoside
-
?
naringin + H2O
4',5,7-trihydroxyflavanone 7-O-beta-D-glucoside + L-rhamnose
show the reaction diagram
-
-
-
-
?
naringin + H2O
4',5,7-trihydroxyflavanone-7-beta-D-glucoside + alpha-L-rhamnose
show the reaction diagram
naringin + H2O
4',5,7-trihydroxyflavanone-7-beta-D-glucoside + L-rhamnose
show the reaction diagram
substrate naringin is preferred over hesperidin
-
-
?
naringin + H2O
?
show the reaction diagram
naringin + H2O
? + alpha-L-rhamnose
show the reaction diagram
preferred substrate, cleavage of the alpha-1,2-linkage
-
-
?
naringin + H2O
beta-D-glucopyranosyl-2,3-dihydro-4',5,7-trihydroxyflavone + alpha-L-rhamnose
show the reaction diagram
naringin + H2O
L-rhamnose + ?
show the reaction diagram
naringin dihydrochalcone + H2O
trilobatin + alpha-L-rhamnose
show the reaction diagram
neohesperidin + H2O
5-hydroxy-2-(3-hydroxy-4-methoxyphenyl)-4-oxo-3,4-dihydro-2H-chromen-7-yl beta-D-glucopyranoside + alpha-L-rhamnose
show the reaction diagram
neohesperidin dihydrochalcone + H2O
3,5-dihydroxy-4-[3-(3-hydroxy-4-methoxyphenyl)propanoyl]phenyl beta-D-glucopyranoside + alpha-L-rhamnose
show the reaction diagram
-
-
-
?
p-nitrophenol-alpha-L-rhamnopyranoside + H2O
p-nitrophenol + alpha-L-rhamnopyranose
show the reaction diagram
p-nitrophenyl alpha-L-rhamnoside + H2O
p-nitrophenol + alpha-L-rhamnose
show the reaction diagram
p-nitrophenyl-alpha-L-arabinofuranoside + H2O
p-nitrophenol + alpha-L-arabinofuranose
show the reaction diagram
-
-
6.1% of activity compared to p-nitrophenyl-alpha-L-rhamnopyranoside
-
?
p-nitrophenyl-alpha-L-rhamnopyranoside + H2O
p-nitrophenol + alpha-L-rhamnopyranose
show the reaction diagram
p-nitrophenyl-beta-D-fucopyranoside + H2O
p-nitrophenol + beta-D-fucopyranose
show the reaction diagram
p-nitrophenyl-beta-D-galactopyranoside + H2O
p-nitrophenol + beta-D-galactopyranose
show the reaction diagram
-
1.6% of activity compared to p-nitrophenyl-alpha-L-rhamnopyranoside
-
?
periplor alpha-L-rhamnoside + H2O
periplogenin + alpha-L-rhamnose
show the reaction diagram
-
-
-
-
?
polygalacturonic acid + H2O
D-galacturonic acid
show the reaction diagram
-
-
-
-
?
poncirin + H2O
poncirein + alpha-L-rhamnose
show the reaction diagram
Bacteroides JY-6
-
-
-
-
?
proscillaridin A + H2O
?
show the reaction diagram
proscillaridin A + H2O
pyranosyl 3,14-dihydroxybufa-4,20,22-trienolid + alpha-L-rhamnose
show the reaction diagram
-
-
-
-
?
quercetin 3-alpha-L-rhamnopyranoside + H2O
quercetin + L-rhamnose
show the reaction diagram
-
31% of activity compared to naringin
-
-
?
quercitrin + H2O
quercetin + alpha-L-rhamnose
show the reaction diagram
quercitrin + H2O
quercetin + L-rhamnose
show the reaction diagram
rhamnogalacturonan tetramer + H2O
?
show the reaction diagram
-
-
-
?
rhamnosyl-glucose + H2O
glucose + alpha-L-rhamnose
show the reaction diagram
robinin + H2O
rhamnose + kaempferol-3-robinoside
show the reaction diagram
-
robinin is identical with kaempferol-3-robinoside-7-rhamnoside
-
?
rutin + H2O
3-glycosylquercetin + alpha-L-rhamnose
show the reaction diagram
rutin + H2O
?
show the reaction diagram
-
63% of activity compared to naringin
-
-
?
rutin + H2O
? + alpha-L-rhamnose
show the reaction diagram
low activity, cleavage of the alpha-1,6-linkage
-
-
?
rutin + H2O
isoquercitrin + alpha-L-rhamnose
show the reaction diagram
rutin + H2O
L-rhamnose + ?
show the reaction diagram
-
-
-
?
saikosaponin C + H2O
(3beta,16beta)-16-hydroxy-13,28-epoxyolean-11-en-3-yl) 6-O-beta-D-glucopyranosyl-beta-D-glucopyranoside + alpha-L-rhamnose
show the reaction diagram
saikosaponin C + H2O
? + alpha-L-rhamnose
show the reaction diagram
scilliglaucosidin alpha-L-rhamnoside + H2O
scilliglaucosidin + alpha-L-rhamnose
show the reaction diagram
-
-
-
-
?
scilliphaeosidin alpha-L-rhamnoside + H2O
scilliphaeosidin + alpha-L-rhamnose
show the reaction diagram
-
-
-
-
?
additional information
?
-