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3.1.1.42: chlorogenate hydrolase

This is an abbreviated version!
For detailed information about chlorogenate hydrolase, go to the full flat file.

Word Map on EC 3.1.1.42

Reaction

chlorogenate
+
H2O
=
caffeate
+
quinate

Synonyms

CHase, chlE, chlorogenase, chlorogenate esterase, chlorogenate hydrolase, chlorogenic acid esterase, chlorogenic acid hydrolase, Cinnamoyl esterase, FAE3, hydrolase, chlorogenate, KX091144

ECTree

     3 Hydrolases
         3.1 Acting on ester bonds
             3.1.1 Carboxylic-ester hydrolases
                3.1.1.42 chlorogenate hydrolase

Application

Application on EC 3.1.1.42 - chlorogenate hydrolase

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APPLICATION
ORGANISM
UNIPROT
COMMENTARY hide
LITERATURE
degradation
food industry
the treatment of the wheat dough with the recombinant enzyme causes a softening. The enzyme does not increase the specific bread volume, but improves dough handling. The enzyme may be effective to improve the taste and digestibility of coffee beverages
synthesis
-
development of a convenient one-pot procedure for conversion of 5-caffeoylquinic acid, from coffee beans, to 3-cyclohexylpropyl caffeate, which exhibits an antiproliferative effect toward various human tumor cells. The procedure comprises of two consecutive reactions by chlorogenate hydrolase from Aspergillus japonicus and Candida antarctica lipase B, and is performed using an ionic liquid, 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide, as the reaction solvent, method optimization, overview. The system provides 12.8 mM 3-cyclohexylpropyl caffeate from 15 mM 5-caffeoylquinic acid with conversion yield of 85.3%. The reaction scarcely proceeds in 1-butyl-3-methylimidazolium tetrafluoroborate, evaluation of several ionic liquids, overview