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1.5.3.12: dihydrobenzophenanthridine oxidase

This is an abbreviated version!
For detailed information about dihydrobenzophenanthridine oxidase, go to the full flat file.

Word Map on EC 1.5.3.12

Reaction

dihydrochelirubine
+
O2
 +
H+
=
chelirubine
 +
H2O2

Synonyms

DBO, DBOX, DHBP, Oxidase, dihydrobenzophenanthridine

ECTree

     1 Oxidoreductases
         1.5 Acting on the CH-NH group of donors
             1.5.3 With oxygen as acceptor
                1.5.3.12 dihydrobenzophenanthridine oxidase

Natural Substrates Products

Natural Substrates Products on EC 1.5.3.12 - dihydrobenzophenanthridine oxidase

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NATURAL SUBSTRATE
NATURAL PRODUCT
REACTION DIAGRAM
ORGANISM
UNIPROT
COMMENTARY
(Substrate) hide
LITERATURE
(Substrate)
COMMENTARY
(Product) hide
LITERATURE
(Product)
REVERSIBILITY
r=reversible
ir=irreversible
?=not specified
(RS)-canadine + O2
berberine + H2O2
show the reaction diagram
-
-
-
-
?
(RS)-tetrahydrocolumbamine + O2
?
show the reaction diagram
-
-
-
-
?
(RS)-tetrahydropalmitine + O2
?
show the reaction diagram
-
-
-
-
?
(RS)-tetrahydropapaverine + O2
papaverine + H2O2
show the reaction diagram
-
-
-
-
?
(S)-scoulerine + O2
?
show the reaction diagram
-
DBOX does not fully aromatize the C-ring of (S)-scoulerine but instead catalyzes a two-electron oxidation
-
-
?
(S)-stylopine + O2
?
show the reaction diagram
-
-
-
-
?
dihydrochelerythrine + O2
chelerythine + H2O2
show the reaction diagram
-
-
-
-
?
Dihydromacarpine + O2
?
show the reaction diagram
-
terminal step in the formation of benzophenanthridine alkaloids containing methylene dioxy substitutions in ring A and D
-
-
?
dihydrosanguinarine + O2
sanguinarine + H2O2
show the reaction diagram
additional information
?
-